低电压条件下水体中诺氟沙星的去除效果及机理-环境工程学报.PDFVIP

第 11卷　 第5 期 环 境 工 程 学 报 Vol. 11,No.5 2 0 1 7 年 5 月 Chinese Journal of Environmental Engineering May 2 0 1 7 低电压条件下水体中诺氟沙星的去除效果及 机理 朱敏杰 ,袁守军1 1,2,∗ 1. 合肥工业大学土木与水利工程学院,合肥 230009 2. 南京大学环境学院污染控制与资源化研究国家重点实验室,南京 210046 摘　 要　 研究低电压条件下诺氟沙星(NOR)的电化学降解去除效果。 结果表明:在 1.3 V外加电压条件下,NOR具有较好 -1 的去除效果,在初始浓度 c =0.09 mmol ·L 时,反应70 h后,NOR去除率为90% 以上;NOR 的去除过程符合伪一级动力 0 学模型。 溶液 pH值、腐殖酸浓度、水质条件等因素均影响 NOR 的电化学降解效果。 中性及弱碱性条件有利于 NOR 的电 化学去除,腐殖酸及天然水体中的有机物会抑制 NOR 的去除效果。 在低电压条件下,NOR 的矿化作用不明显,NOR 的电 化学降解过程中伴随着大量有机中间产物生成。 关键词　 电化学;诺氟沙星;低电压;腐殖酸;污水 中图分类号　 X703　　 文献标识码　 A　　 文章编号　 1673-9108(2017)05-2677-07　　 DOI　 10.12030/ j.cjee.201601169 Removal effect of norfloxacin from aqueous solution under the condition of low voltage and its mechanism ZHU Minjie ,YUAN Shoujun1 1,2,∗ 1.School of Civil and Hydraulic Engineering,Hefei University of Technology,Hefei 230009,China 2.State Key Laboratory of Pollution Control and Resource Reuse,School of the Environment,Nanjing University,Nanjing 210046,China Abstract　 Removal of norfloxacin (NOR) from aqueous solution was studied electrochemically at weak voltage. The results showed that the removal of NOR was efficient at 1.3 V. A removal rate of90% was achieved after70 -1 h of reaction using an initial concentration of0.09 mmol ·L . The removal of NOR accordswith a pseudo-first- order kinetic model,where the pH value,humic acid,and water quality were the main factors that affected the removal of NOR. A relatively higher removal rate of NOR was observed in both neutral and alkaline conditions. Humic acid and organic matters in natural water inhibited the removal efficiency of NOR. The mineralization of NOR wasnot obvious during the electrochemical reaction atweak voltage,which resulted in a larg