气体水合物生成机理分析.pdfVIP

气体水合物生成机理分析 袁争印 梁坤峰 王林 (河南科技大学制冷与空调技术研究所，河南洛阳，471 3) 综述了凝固点原理、气体水合物的结构及生成机理的基本观点，基于此，提出了一些问题：笼状 摘 要： 结构中，客体分子与水分子之间为什么靠范德华力维系相对稳定，一般客体分子均带有 H 原子，其中的 H 原子为什么不能与水分子的 O 原子形成氢键以维系结构稳定？笼状结构是以客体分子为核心逐渐长大的， 还是笼状结构形成之后，客体分子被选择性地进入其空穴中？带电性的客体分子进入笼状结构后，能否有 可能形成胶体？不同客体分子生成水合物的平衡压力及温度有较大的不同，这些宏观因素的微观解释又是 什么？水合物制备过程中，扰动量及过冷度该怎样控制才能达到制备效果最佳？ 气体水合物，凝固点，笼形结构，扰动，过冷度，平衡压力 关键词： Mechanism analysis of gas hydrate formation Yuan Zhengyin Liang Kunfeng Wang Lin (Institute of refrigeration and air conditioning technology Henan University of Science and Technology, Henan Luoyang, 471003, China) Abstract The basic idea of freezing point are reviewed in this paper, the basic ideas of the structure and generation mechanism of gas hydrate, and according to these basic ideas, put forward some questions: Cage structure, the object with water molecules between why by van der Waals force to maintain relative stability, the general object of molecules with H atoms, why cant the H atoms O atoms to form hydrogen bond with water molecules to maintain structural stability?Cage structure is the core object molecules gradually grew up, or cage structure formation, the object molecules are selectively into the hole? Charged object molecules enter the cage structure, whether could form gel? Different object molecules to generate hydrate equilibrium pressure and temperature has great different, these micro macro factors explain? Key words gas hydrates; freezing point; cage structure; destabilizat