不同组成纤维素热解炭的燃烧行为分析-烟草科技.PDF

2017 年7 月 烟草科技 Jul. 2017 第50 卷第7 期 Tobacco Science Technology Vol. 50 No. 7 不同组成纤维素热解炭的燃烧行为分析 1 1 1 *2 2 *1 王 菁 ，蔡佳校 ，张 柯 ，陈超英 ，郑赛晶 ，李 斌 1. 中国烟草总公司郑州烟草研究院，郑州高新技术产业开发区枫杨街2号 450001 2. 上海新型烟草制品研究院，上海市大连路789号 200082 摘要：选取纤维素作为原料，分别在350 ℃、550 ℃、750 ℃和950 ℃下热解制备得到4 种纤维素热解炭， 通过组成和燃烧特性分析分别考察了单组分热解炭及其相互混合得到的炭材料的燃烧特性。结果表 明：①随着热解温度的提高，热解炭样品中的碳元素含量逐渐升高，氢和氧元素含量逐渐下降，同时热解 炭产率也随之降低；②随着热解温度的提高，热解炭样品中固定碳含量和高位热值逐渐升高，挥发分含 量逐渐降低；③热解炭燃烧特性曲线随热解温度提高逐渐往高温区移动，着火温度、燃尽温度、DTG 曲线 峰值温度均逐渐提高；④将具有不同燃烧特性的纤维素热解炭进行适当的混合，能够得到具有低引燃 性、高放热量、宽放热区间且燃烧过程均匀稳定的炭质热源材料。 关键词：炭加热卷烟；纤维素；热解炭；热重分析；燃烧特性 中图分类号：TS412 文献标志码：A 文章编号：1002-0861 （2017 ）07-0076-06 Analyses on combustion behaviors of cellulose pyrochars of different compositions 1 1 1 *2 2 * 1 WANG Jing , CAI Jiaxiao , ZHANG Ke , CHEN Chaoying , ZHENG Saijing , LI Bin 1. Zhengzhou Tobacco Research Institute of CNTC, Zhengzhou 450001, China 2. Shanghai New Type Tobacco Product Research Institute of CNTC, Shanghai 200082, China Abstract: Taking cellulose as carbon precursor, four kinds of cellulose pyrochars were prepared at 350 ℃, 550 ℃, 750 ℃, and 950 ℃, respectively. The composition and combustion characteristics of each pyrochar and their mixtures were investigated. The results showed that: 1) With the rise of pyrolysis temperature, the carbon content in pyrochars increased gradually, the contents of hydrogen and oxygen decreased gradually, and the yield of pyrochars reduced as well. 2) The fixed carbon content and high heat value of pyrochars increased and the volatile component contents decreased along with the rise of pyrolysis temperature. 3) Thermogravimetric