材料合成化学课件(1-2) Introdution (color).pdf

Five keywords of materials synthesis (材料合成五字诀） 知(Knowledge): physical and chemical constants; safety data; basics of the preparation procedure. MSDS ICSC 常(Common sense): should not violate current laws. 变(修) (Modification): make changes when necessary. 交(Hybrid): mix different methods/routes/conditions. 试(Trial): trial-and-error. “合成五字言，常试知交变” Examples -- flavor of materials synthesis Co-precipitation – RE O -doped (Bi O ) 2 3 2 3 Citrate combustion method – synthesis of YBCO and BSCCO Microwave plasma chemical vapor deposition – YBCO thin films Vacuum sputtering – deposition of YBCO thin films (Physical route) Solid state reaction – preparation of Sb O -doped SnO thick films 2 3 2 Chemical spray deposition (CSD) – deposition of SnO2 thin films Aqueous sol-gel method – synthesis of LSCO powders and bulk Organic sol-gel method – synthesis of LSCO powders and bulk Examples of materials synthesis Electrostatic Spray Deposition (ESD) – fabrication of a series of functional ceramic thin-films (Li(Co,Ni)O , LiMn O ,YSZ, 2 2 4 LaMnO , SnO , carbon, PbTiO , polymer, etc.) 3 2 3 Flame-Assisted Ultrasonic Spray Pyrolysis (FAUSP) – preparation of ZrO2 and YSZ fine powders. Solid state reaction – preparation of doped-Li Ti O ; LiCoPO ; 4 5 12 4 (La,Sr)(Ta,Zr)O . 3 Chemical Vapor Transport and Condensation (CVTC) – nano ZnO Reinforced carbon-carbon (RCC) – for space shuttles Alchemy – “丹炉九还掷千金” ( ［明］凌蒙初) Oxygen-conduscting Bi O Oxygen-conduscting Bi O