常见标准热力学数据29815K.doc

PAGE PAGE 5hfgjghjhkghk附 录附录1 常见标准热力学数据(298.15K)物 质状态ΔfHm?/(kJ·mol-1)ΔfGm?/(kJ·mol-1)Sm?/(J·mol-1·K-1)Ags0042.6Ag+aq105.677.172.7AgBrs-100.4-96.9107.1AgCls-127.0-109.896.3AgIs-61.8-66.2115.5AgNO3s-124.4-33.4140.9Ag2Os-31.1-11.2121.3Als0028.3Al3+aq-531.0-485.0-321.7AlCl3s-704.2-628.8110.7Al(OH)3s-1284-130671Br2l00152.2Br－aq-121.6-104.082.4C(石墨)s005.7C(金刚石)s1.92.92.4Cas0041.6Ca2+aq-542.8-553.6-53.1CaC2s-59.8-64.970.0CaCO3(方解石)s-1207.6-1129.191.7CaCl2s-795.4-748.8108.4CaOs-634.9-603.338.1Ca(OH)2s-985.2-897.583.4Cl2g00223.1Cl-aq-167.2-131.256.5ClO3-aq-104.0-8.0162.3ClO4-aq-129.3-8.5182.0CCl4l-128.2-62.6216.2CH4g-74.6-50.5186.3CH3OHl-239.2-166.6126.8CO(NH2)2s-333.1-196.8104.6CH3NH2g-22.532.7242.9C2H2g227.4209.9200.9C2H4g52.468.4219.3CH3CHOl-192.2-127.6160.2CH3COOHl-484.3-389.9159.8C2H6g-84.0-32.0229.2C2H5OHl-277.6-174.8160.7(CH3)2COl-248.4-152.7199.8物 质状态ΔfHm?/(kJ·mol-1)ΔfGm?/(kJ·mol-1)Sm?/(J·mol-1·K-1)C3H8g-103.8-23.4270.3C6H6l49.1124.5173.4g82.9129.7269.2COg-110.5-137.2197.7CO2g-393.5-394.4213.8CO32-aq-677.1-527.8-56.9CrO42-aq-881.2-727.850.2Cr2O3s-1139.7-1058.181.2Cus0033.2Cu2+aq64.865.5-99.6CuOs-157.3-129.742.6Cu2Os-168.6-146.093.1CuSs-53.1-53.666.5F2g00202.8F－aq-332.6-278.8-13.8Fes0027.3Fe2+aq-89.1-78.9-137.7Fe3+aq-48.5-4.7-315.9Fe2O3s-824.2-742.287.4FeSO4s-928.4-820.8107.5H2g00130.7H+aq000HBrg-36.3-53.4198.7HClg-92.3-95.3186.9HCO3-aq-692.0-586.891.2HCHOg-108.6-102.5218.8HCOOHl-425.0-361.4129.0HFg-273.3-275.4173.8HIg26.51.7206.6HNO3l-174.1-80.7155.6H2Ol-285.8-237.170.0g-241.8-228.6188.8H2O2l-187.8-120.4109.6g-136.3-105.6232.7H2Sg-20.6-33.4205.8H2SO4l-814.0-690.0156.9HgOs-90.8-58.570.3I2s00116.1g62.419.3260.7I-aq-55.2-51.6111.3Ks0064.7K+aq-252.4-283.3102.5物 质状态ΔfHm?/(kJ·mol-1)ΔfGm?/(kJ·mol-1)Sm?/(J·mol-1·K-1)KCls-436.5-408.582.6KClO3s-397.7-296.3143.1Li+aq-278.5-293.313.4Mgs0032.7Mg2+aq-466.9-454.8-138.1MgCl2s-641.3-591.889.6MgOs-601.6-569.327.0Mg(OH)2s-924.5-833.563.2MgSO4s-1284.9-1170.691.6Mn2+aq-220.8-228.1-73.6MnO2s-520.0-465.153.1MnO4-aq-541.4-447.21