含全氟烃基的联苯酯类液晶的合成及其介晶性Synthesisand.PDF

2007 年第65 卷 化 学 学 报 Vol. 65, 2007 第21 期, 2499～2504 ACTA CHIMICA SINICA No. 21, 2499～2504 ·研究简报· 含全氟烃基的联苯酯类液晶的合成及其介晶性 汪必琴 王新玲 赵可清* 胡 平 ( 四川师范大学化学与材料科学学院 成都 610066) 摘要 全氟烃或半氟烃链无手性液晶化合物可能呈现铁电液晶性, 具有较大的学术及应用价值而受到研究人员的重 视. 合成了全氟己基苯甲酸联苯酯类液晶化合物: ROC H C H O CC H C F (3a ～3e), C H C H C H O CC H C F 6 4 6 4 2 6 4 6 13 3 7 6 4 6 4 2 6 4 6 13 (6a)及其烃衍生物. 用差示扫描量热法(DSC)和偏光显微镜(POM)对其介晶性研究发现: 烃衍生物呈有序度较低的向列 相, 熔点较高, 清亮点较低, 液晶相较窄. 全氟烃基取代的化合物出现多个有序度较高的近晶相, 熔点较低, 清亮点高, 介晶相温度范围宽. 关键词 液晶; 4-丙基联苯酚; 全氟烃链; 亲氟效应; 疏氟效应 Synthesis and Mesomorphism of Perfluoroalkyl Chain Containing Biphenyl Liquid Crystals WANG, Bi-Qin WANG, Xin-Ling ZHAO, Ke-Qing* HU, Ping (College of Chemistry and Material Sciences, Sichuan Normal University, Chengdu 610066) Abstract Perfluorinated or semi-perfluorinated alkyl chain containing achiral liquid crystals can display ferroelectric liquid crystalline properties, which have great potential applications to industry, therefore have at- tracted the attention of researchers. In this report, biphenylyl 4-perfluorohexylbenzoate liquid crystalline com- pounds ROC H C H O CC H C F and C H C H C H O CC H C F , (R＝C H ＋ , n ＝6, 8, 10, 12, 16) 6 4 6 4 2 6 4 6 13 3 7 6 4 6 4 2 6 4 6 13 n 2n 1 have been synthesized. Their mesogenic behavior was investigated with differential scanning calorimetry (DSC) and po