氟碳改性聚丙烯酰胺共聚物的溶液性质-上海有机化学研究所.PDFVIP

2002 年第 60 卷 化 学 学 报 Vol. 60 , 2002 第 9 期 , 1707～1711 ACTA CHIMICA SINICA No. 9 , 1707 ～1711 氟碳改性聚丙烯酰胺共聚物的溶液性质 步怀天a 　　杨振忠 , a 　　章云祥b ( a 中国科学院化学研究所分子科学中心 　高分子物理与化学国家重点实验室 　北京 100080) ( b 中国科学院上海有机化学研究所 　上海 200032) 摘要 　研究了氟碳链改性的聚丙烯酰胺水溶液的溶液性质及其对盐浓度的依赖性 ,重点考察了氟碳疏水组分含量、 盐浓度对特性粘数的影响 , 以及粘度随剪切速率和温度的变化关系. 结果表明聚合物溶液的粘度随盐的引入而增 大 ,但在两种溶液中最小值对应的共聚单体含量一致. 随温度的增加 ,共聚物溶液粘度依次出现了最小和最大值. 所 有实验结果均归于溶液中存在的疏水和氢键两种相反作用的综合结果. 关键词 　聚丙烯酰胺 ,氟碳链改性 ,疏水缔合作用 ,氢键 ,流变行为 Solution Behavior of Fluorocarbonmodified Polyacrylamide Copolymers BU , HuaiTian a 　　YANG, ZhenZhong , a 　　ZHANG, YunXiang b ( a State Key Laboratory of Polymer Physics and Chemistry , Centerfor Molecular Science , ) Institute of Chemistry , Chinese Academy of Sciences , Beijing 100080 ( b Institute of Organic Chemistry , Chinese Academy of Sciences , Shanghai 200032) Abstract 　The properties of fluorocarbonmodified polyacrylamide aqueous solutions are investigated , including rheological behavior , intrinsic viscosity and their dependence on temperature and the addition of salts. It is found that hydrogen bond strength and hydrophobic association of the solutions are remarkably influenced by the content and chemical structure of the hydrophobic comonomers. The viscosity reaches a minimum when molar content of the comonomers is 0. 14 % , and all samples’viscosity increases with the addition of salts. With the incre