两步反应梯阶转化原理及其应用.pdfVIP

两步反应梯阶转化原理及其应用 黄 伟* （太原理工大学煤化工研究所，煤科学与技术教育部和山西省重点实验室山西 太 原030024） 摘要 随着人类对环境问题的日益重视，发展绿色化学工艺正在成为化学家追求的 目标。然而，由于在实际过程中存在着热、动力学、化学计量以及技术经济性等诸 多限制，使多数化学过程难以实现理想的绿色化。本文通过对两步反应梯阶转化原 理的介绍，特别是在CH -CO 直接转化的应用及两步梯阶转化反应器的设计，试图阐 4 2 述如何基于原料化学结构特性的反应设计、工艺设计和过程设计克服实际“限制”， 实现理想的化学转化，把绿色化学的追求变成可实施的行动。 关键词：梯阶转化；甲烷；二氧化碳；反应器 Principle of two-step stepwise conversion and its application HUANG Wei (Key Laboratory of Coal Science and Technology, Ministry of Education and Shanxi Province; Institute Coal Chemical Engineering; Taiyuan University of Technology, Taiyuan 030024, Shanxi, China) Abstract ：Along with the increasing attention to environmental issues ，the development of green chemical technology is becoming a goal pursued by chemists. However，Since there is restrictions in real processes from thermodynamics, dynamics, stoichiometrics, as well as technic and economy ，so that it is difficult to achieve the ideal of green for the majority of the chemical processes. By introducing the principle of two-step stepwise conversion ，especially in the application of direct conversion into acetic acid from CH -CO and the design of two-step stepwise reactor ，this paper trys to set out how to 4 2 *联系人：黄伟. （1962—），男，博士生导师，教授. 基金项目：国家自然科学基金）和973 计划课题（2005CB221204 ）资助 Corresponding author: Prof. HUANG Wei. E-mail:huangwei@tyut.edu.cn Foundation item: supported by the National Natural Science Foundation of China and 973 Project (2005CB2212 overcome the actual limit and to achieve the desired chemical conversion through the reaction design, technology design and process design based on the chemical structure characteristics of raw material, converting the pursuit of g