电镀镍钨合金之腐蚀与磨耗行为研究.pdfVIP

電鍍鎳鎢合金之腐蝕與磨耗行為研究 防蝕工程　第二十六卷第一期　第1 ~ 8 頁　2012 年3 月 Journal of Chinese Corrosion Engineering, Vol. 26, No. 1, pp. 1 ~ 8 (2012) 1 1 1 1 2 陳信宏 、賴嘉宏 、吳孟諺 、李弘彬* 、李春穎 A Study on the Corrosion and Wear Behavior of Electrodeposited Ni-W Coatings 1 1 1 1 2 S. H. Chen , J. H. Lai , M. Y. Wu , H. B. Lee* , C. Y. Lee Received 29 October 2010; received in revised form 10 February 2012; accepted 14 February 2012 本研究利用梢與環(block-on-ring)腐蝕磨耗系統研究電鍍鎳鎢合金之腐蝕與磨耗行為。 研究結果顯示電鍍鎳鎢合金在 5 wt%鹽水溶液中利用動態電位極化曲線量測有鈍化行為， 隨極化電位提高，無論磨耗速率及表面鎢含量兩者都增加；相反地，摩擦係數隨極化電位 增高而下降。經 FESEM 觀察鍍層表面出現細小蝕孔與龜裂，由 XPS 分析鍍層表面形成鈍 化膜，透過TEM 觀察鎳鎢合金腐蝕區出現微裂紋結構。 關鍵詞：電鍍鎳鎢合金；腐蝕與磨耗；摩擦係數。 ABSTRACT In this study, a block-on-ring wear tester was employed to investigate the tribocorrosion behavior of electrodeposited Ni-W coatings. Passivation of the Ni-W alloy was observed according to the potentiodynamic polarization curve obtained in a 5 wt% NaCl solution. The result showed that with an increase in the applied overpotential, both the wear rate and the surface W-content of the coating increased. On the other hand, the accompanying coefficient of friction decreased with the increasing overpotential. The FESEM micrograph showed that small pits and cracks appeared on the tested specimen. This micro-cracking phenomenon was also observed in the corroded zone of the N