粒料法合成聚氨酯分散体及性能的研究-高校化学工程学报.PDF

26 2 No.2 Vol.26 2012 4 Journal of Chemical Engineering of Chinese Universities Apr . 2012  1003-9015(2012)02-0290-06  , ( , 510640) (PTMG)(IPDI) 1,4-(BDO) (DMPA)40 (PUD) PUD ζ30~ 60 mV1100 mPas PUD 3.15 ~6.67 DMA TQ 630.1 TQ323.8 A Sythesis and Properties of Polymerthane Dispersions Synthesized by Pellet Process XU Zhi-zheng, SUN Dong-cheng (School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China) Abstract Polyurethane ionomeric polymer pellets were synthesized by the pellet process with polytetramethylene glycol (PTMG) as soft segmentisophorone diisocyanate (IPDI) and 1,4-butanediol(BDO) as hard segments, and dimethylolpropionic acid (DMPA) as hydrophilic monomer, and the polyuerthane dispersion(PUDs) with solid content about 40% were obtained. The properties of PUDs and their films were characterized, and the results show that the Zeta potentials of PUDs are between –30 mV and –60 mV and the viscosity less than 1100 mPas. With the increase of hydrophilic group content, the average particle size decreases, the particle size distribution narrows and the viscosity increases; while the average particle size decreases, the particle size distribution becomes broader and the viscosity decreases when hard segment content increases. TEM micrographs show that the sizes of the spherical shape pellet particles are nonuniform. Water absorption ratio of all the PUDs films are between 3.15 and 6.67 . The results o