共轭高分子材料荧光颜色的调节机理及方法.docxVIP

共轭高分子材料荧光颜色的调节机理及方法*陈云邵亚范丽娟＊＊(苏州大学材料与化学化工学部高分子科学与工程系 江苏省先进功能高分子材料设计及应用重点实验室苏州 215123)摘 要 近年来，共轭高分子作为荧光材料的研究受到越来越多的关注。共轭高分子相对于小分子发光材料在材料加工和发光性能上均具有极大的优势，从而在生物成像、传感、编码和光电材料等方面均有良好的 应用前景，而其发光颜色的调节在某些应用中是极为重要的。本文首先对共轭高分子荧光颜色调节的两大 类机理进行了阐述:直接调节共轭聚合物发光体系的能隙以改变发光颜色，或者将具有不同荧光颜色的材料 发出的光叠加获得新的表观颜色。我们还对具体的调节手段进行了初步分类，包括物理共混法、共聚法、改 变聚合物主链或侧基结构，以及改变共轭高分子聚集态等方法;在列举具体调节手段同时还引入了共轭高分 子体系的实例说明，并对其中调节荧光颜色的可能机理进行了探讨。关键词 共轭高分子 荧光 颜色调节 机理中图分类号:O631. 2 + 4; O632 文献标识码: A 文章编号: 1005-281X(2014)11-1801-10Fluorescent Color Tuning of Conjugated Polymer Materials: Mechanisms andMethods*Chen Yun Shao Ya Fan Lijuan＊＊(Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application，Department of Polymer Science and Engineering ， College of Chemistry ， Chemical Engineering and M aterials Science， Soochow University ，Suzhou 215123，China)AbstractConjugated polymers have received ever-increasing attention as fluorescent materials． They havemany advantages compared w ith small-molecular fluorescent materials． As materials，conjugated polymers can befabricated into different forms，such as thin films by spinning coating or drop casting ，nano -/ micro - fibers by electrospinning ，nano -/ micro - spheres，and micelle / vesicle / microtubule / nanoparticles by self -assembly ． The great flexibility of conjugated polymers in processing makes it possible for them to meet the demands of different applications． With regard to the photophysics，the broader absorption allow s conjugated polymers to be excited by different light sources． In addition，the high resistance to the photobleaching ，or photostability ，guarantees a long lifetime w hen conjugated polymers in real applications． These advantages allow conjugated polymers to be used in different fields，ranging from fluorescent bioimaging and sensors，to optical encoding and photoelectric displays． Some applications，such as encoding and display ，require that the fluorescent materials have va