刺激响应性综述csr.pdfVIP

Chem Soc Rev REVIEW ARTICLE View Article Online View Journal | View Issue . Artificial switchable catalysts e c n e c ab a a i Victor Blanco,† David A. Leigh* and Vanesa Marcos† L Cite this: Chem. Soc. Rev., 2015, . d 6 e 44, 5341 5 t r : o 7 p Catalysis is key to the effective and efficient transformation of readily available building blocks into high 5 : n 8 U value functional molecules and materials. For many years research in this field has largely focussed on 0 7 0. 1 3 the invention of new catalysts and the optimization of their performance to achieve high conversions 0 2 n / o 7 i and/or selectivities. However, inspired by Nature, chemists are beginning to turn their attention to the t 0 u / b 8 i development of catalysts whose activity in different chemical processes can be switched by an external 2 r t n t stimulus. Potential applications include using the states of multiple switchable catalysts to control o A d s e n Received 2nd February 2015 sequences of transformations, producing different products from a pool of building bloc