轶纶_聚酰亚胺短纤维耐化学性研究.docxVIP

轶纶?聚酰亚胺短纤维耐化学性研究张国慧，张娜，杨诚，卢晶，丁孟贤（长春高琦聚酰亚胺材料有限公司，长春130103）要:用不同浓度硝酸、硫酸和氢氧化钠溶液在不同温度下处理不同的时间，分别对轶纶?聚酰亚胺短纤维、进口聚酰亚胺摘短纤维及聚酰胺酰亚胺短纤维抗断裂强度保持情况、水蒸汽中处理24 h短纤维的抗断裂强度保持情况和滤料的收缩情况进行耐化学性试验。结果表明，轶纶?短纤维耐氢氧化钠性能要明显好于进口聚酰亚胺短纤维和聚酰胺酰亚胺短纤维，长期耐硫 酸性能及耐硝酸性能略好于进口聚酰亚胺短纤维，并且都好于聚酰胺酰亚胺短纤维，特别是轶纶?短纤维耐受高浓度的硫酸 及硝酸的性能要好于其它两种短纤维，轶纶?短纤维及滤料耐水蒸汽性能要好于其它几种短纤维及滤料。同时，对轶纶?短 纤维进行了红外分析，测试结果表明它的结构在酸碱处理前后并没有变化。 关键词:聚酰亚胺；轶纶?聚酰亚胺短纤维；聚酰胺酰亚胺短纤维；耐化学性；研究中图分类号: TQ342.731文献标识码: A文章编号: 1007-9815（2012）04-0025-10Study on the chemical resistance of Yilun? polyimide staple fiberZHANG Guo-hui,ZHANG Na,YANG Cheng,LU Jing,DING Meng-xian(Changchun HiPolyKing Co., Ltd,Changchun130103China)Abstract: The chemical resistance of Yilun? polyimide staple fibers, exported polyimide staple fibers and polyamide imide staple fibers was investigated in various concentration of sodium hydroxide, nitric acid, sulphuric acid at different temperature and time and the resistance in boiling water and water vapour at different time. The results indicated that the alkali resistance of Yilun? staple fibers is higher than that of imported polyimide staple fibers and polyamide imide, the dilute acids resistance is comparable for Yilun and the other fibers. However, the resistance of Yilun? staple fibers in concentrated acids is much higher than the other fibers. The resistance of Yilun? staple fibers and filter materials in water vapour is better than the other fibers and filter materials. By infrared analysis, testresults show that the structure of fibers does not change apparently after treating in dilute acid and alkali.Key words: polyimide; Yilun? polyimide staple fibers;polyamide imide staple fibers, chemical resistance; study随着环保事业的发展，钢铁、水泥、电厂等企业越来越重视烟尘的过滤和排放。在烟尘过 滤中起重要作用的是纤维滤料。纤维滤料性能的 优劣直接关系到纤维过滤器的除尘性能和使用寿 命。而纤维滤料的性能主要靠纤维的物化性能来 体现。工业烟尘中含有一定量的酸性、碱性物质 和水蒸汽，而酸性和碱性物质对纤维及其制品均会发生腐蚀作用。因此要求纤维具有一定的耐酸、碱及水蒸汽性能。但是酸碱对纤维腐蚀程度 要视酸碱种类、浓度和接触时间长短而定。因此 研究纤维的耐化学腐蚀性，对用于工业烟尘过滤 滤料具有指导作用。作者加强了纤维所处的酸 碱、沸水及蒸汽环境，探讨了酸、碱浓度和温度 对其力学性能的影响。收稿日期: 2012-07-27作者简介:张国慧（1973-），