生物浸铜液论文：高铁生物浸铜液回收铜及除铁工艺研究.docVIP

生物浸铜液论文：高铁生物浸铜液回收铜及除铁工艺研究 【中文摘要】生物浸铜技术能经济有效的处理低品位、难回收铜矿,应用前景广阔。但生物浸铜液含铁较高时,不利于铜的萃取。本文以高铁生物浸铜液为原料,采用硫化沉淀-双氧水氧化浸出-蒸发浓缩工艺制备硫酸铜,并采用热熔法回收渣中的单质硫。再分别采用氧化沉淀法和黄钠铁矾法除去回收铜后液中的铁,废水实现循环利用。具体研究结果如下：与硫化钠比较,硫化氢沉铜所需硫化剂用量较少,不产生氢氧化铁沉淀,更适合处理生物浸铜液。当硫化氢与铜的物质的量比为1.9：1,pH值为1,反应温度为30℃,搅拌速度为500r-min-1,反应时间为3h时,硫化氢处理生物浸铜液,其铜沉淀率接近100%,Fe3+ 【英文摘要】The bioleaching copper technology is an economical effective method for treating low grade and difficult recovery copper ores, which has a broad application prospect. But the iron content of copper bioleaching solution is higher, which has an side effect on the solvent extraction of copper.Copper sulfate pentahydrate was prepared from copper bioleaching solution by sulfide precipitation, hydrogen peroxide leaching and evaporative concentration process, and the elemental sulfur was recovered from slags by hot melting method. Futhermore, the iron of the solution after recovering copper was removed by oxidizing sedimentation method and sodium jarosite method and the wastewater was recycled.Compared with Na2S method, treating copper bioleaching solution by H2S method needs less agent, and no Fe(OH)3 gels are formed.The precipitation rate of Cu was 100% and the reduction of Fe3+ was 91% by H2S treatment when the molar ratio of H2S:Cu was 1.9:1, the solution pH value was 1, the reaction temperature was 30℃, and the reaction time was 3h. The main phase of sediments were both CuS and S, of which the Cu content was 45%.Copper sulfide sediment was leached by hydrogen peroxide and sulphuric acid. The copper leaching rate was 92.1% under the conditions of molar ratio of hydrogen peroxide with copper, reaction temperature, liquid-solid ratio, concentration of sulfuric acid, and reaction time were set to be 6.4:1,50℃,15:1,3mol·L-1 and 2h, respectively. CuSO4·5H2O was obtained by evaporative cooling crystallization process when the volume of solution after evaporation and concentration was 1/2 of the stock solution under the cooling temperature of 6℃. The purity of o