弱相互作用力驱动的鸟嘌呤核苷自组装研究.pdf

I 91．2．61．41．4．1 目录 第三章静电相互作用诱导的鸟嘌呤核苷衍生物自组装 3．1前言………………………………………………………………………………49 3．2实验方法…………………………………………………………………………52 3．3结果与讨论………………………………………………………………………52 3．3．1 DMG自身的组装行为…………………………………………………………52 3．3．2 PyG与DMG混合物在基态的组装……………………………………………54 3．3．3 PyG与DMG混合物在激发态的组装…………………………………………57 3．4结论………………………………………………………………………………………………………．．61 3．5附图………………………………………………………………………………63 3．6参考文献…………………………………………………………………………78 第四章与硼酸结合的鸟嘌呤核苷在水溶液中的自组装 4．1前言………………………………………………………………………………83 4．1．1水溶液中的G．四链体超分子自组装…………………………………………83 4．1．2硼酸与糖(--醇化合物)的络合原理…………………………………………83 4．2实验方法…………………………………………………………………………87 4．3结果与讨论………………………………………………………………………87 4．3．1苯硼酸与鸟苷形成凝胶的结果及讨论………………………………………87 4．3．2 PypyBA与鸟苷于水溶液中组装结果及讨论………………………………．．90 4．4结论……………………………………………………………………………………………………98 00 4．5附图………………………………………………………………………………1 4．6参考文献………………………………………………………………………一106 附录 论文创新点…………………………………………………………………………108 本文涉及的符号和缩略语…………………………………………………………109 攻读硕士学位期间所获奖项………………………………………………………110 1 攻读硕士学位期间发表和交流的论文……………………………………………11 致谢…………………………………………………………………………………112 NewNucleosideNucleosides………………………………．1NanostructuresAbstractAbstractAssembliesMetalWater．……………………………………………4MaterialsMethods…………………………………………………………………………………………………．．35BiosensorsBasedDerivativesDerivativesDerivativesDNADissertation……………………………………………………………………22Derivatives…………………………35Derivatives…………………………39PotassiumContentsGuanosineGuanosineGuanosineGuanosineExtractants……………………．．1GuanosineGuanosineasGuanosineEnantiomericCharacterizations………………………………………………………………35onOtherChinese……………………………………………………………………………………．iResearchCharacterizationsCharacterizationsContentsRecentOtherSolvent…………………．．6SelectiveSelf-assembliesScience．．．．．．．．．．．．．．．．．．．．18andSensors…．…．……………………．………．…．………．……．……．………．…．…．19andandandof6ofofSelf-assembled2．12．22．42．4．12．4．22．5ofofofformSec