含N微孔SAPO34分子筛的固体核磁MAS+NMR表征.pdf

石油学报(石油|illlZ．) 2006年lO月 ACTAPETROLElSINICA(PETR01．EUMPROCESSINGSECTION) 增予 文章编号2006)增刊一0139—03 含N微孔SAPO一34分子筛的固体核磁(MASNMR)表征 MAGICANGLESPINNINGNMRINVESTIGATIONSONN-CONTAINING MICRoPoRoUSSAPo一34 MoLECULARSIEVES 关新新“2，武光军1，章福祥1，关乃佳1 GUANXin—xinl～，WU Fu Guang—junl．ZHANG Nai-jial xian91．GUAN (1南开大学新催化材料科学研究所．天津300071；2．郑州大学工业催化研究所，河南郑州450052) (1．[mtitute MaterialsScience，Nankai o，Ne∞C=talytic Uni口ersltyt Tia埘1H300071，China； 2．Institute ofIndustrial 450052，China) Catalysis，ZhengzhouUni僻rsity，Zh删gzhou 摘要：采用高温下NH 核磁谱等表征方法对SAPO 34分子筛氮化后的结构进行了研究。结果表明，SAPO34分子筛经高温氯化后．仍 具有良好的晶体结构和结晶度；同时，分子筛骨架Al原子和P原子的化学位移发生了明显变化，说明 SAPO-34分子筛氮化后含N基团已进八分子筛骨架中。 关键葡：sAPO一34分子筛；氮化}表征；XRD；MASNMR 中圈分类号：TQll6．2文献标识码：A eontaiSAPO一34 molecularsieveswere nitridationofSAP0-34 Abstract：Nitrogenrfing mieroporous by prepared molecularsieveswithammoniaatelevated The instructureofthe temperature nitrogen—containing changes SAPD34molecularsieveswere meansofX diffraction．27AIMASNMRand”PMASNMR．It investigatedby ray wasfoundthatthe still well—definedstructureand afternhridationat samplespossessed higherystallinity high had intothe ofSAPO-34molecularsieves framework temperatures．Nitrogen—containingspeciesincorporated detected27Al 31 hy andPMASNMR．