高等有机合成 2-8-Reactions of Carbon Nucleophiles with Carbonyl Compounds.pptVIP

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高等有机合成 2-8-Reactions of Carbon Nucleophiles with Carbonyl Compounds.ppt

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高等有机合成 2-8-Reactions of Carbon Nucleophiles with Carbonyl Compounds

Reactions of CarbonNucleophiles with CarbonylCompounds Prof. Yue Chen (陈悦) Oct. 31th, 2008 2.6.1. Conjugate Addition of Enolates 2.6.1. Conjugate Addition of Enolates 2.6.1. Conjugate Addition of Enolates 2.6.1. Conjugate Addition of Enolates 2.6.1. Conjugate Addition of Enolates 2.6.1. Conjugate Addition of Enolates 2.6.1. Conjugate Addition of Enolates 2.6.1. Conjugate Addition of Enolates 2.6.2. Conjugate Addition with Tandem Alkylation 2.6.3. Conjugate Addition by Enolate Equivalents 2.6.3. Conjugate Addition by Enolate Equivalents A tendency to favor anti diastereoselectivity, regardless of the silyl enol ether configuration 2.6.3. Conjugate Addition by Enolate Equivalents 2.6.4. Control of Facial Selectivity in Conjugate Addition Reactions 2.6.4. Control of Facial Selectivity in Conjugate Addition Reactions 2.6.4. Control of Facial Selectivity in Conjugate Addition Reactions 2.6.4. Control of Facial Selectivity in Conjugate Addition Reactions * 2.4.1.1. Olefination Reactions Involving Phosphonium Ylides 2.4.1.1. Olefination Reactions Involving Phosphonium Ylides 2.4.1.2. Olefination Reactions Involving Phosphonate Anions 2.4.1.2. Olefination Reactions Involving Phosphonate Anions. Wadsworth-Emmons reaction- Usually E isomer formed 2.4.1.2. Olefination Reactions Involving Phosphonate Anions. 2.4.1.2. Olefination Reactions Involving Phosphonate Anions. 2.4.1.2. Olefination Reactions Involving Phosphonate Anions. 2.4.1.2. Olefination Reactions Involving Phosphonate Anions. 2.4.1.2. Olefination Reactions Involving Phosphonate Anions. 2.4.1.2. Olefination Reactions Involving Phosphonate Anions. 2.4.2. Reactions of -Trimethylsilylcarbanions with Carbonyl Compounds Peterson reaction 2.4.2. Reactions of -Trimethylsilylcarbanions with Carbonyl Compounds 2.4.2. Reactions of -Trimethylsilylcarbanions with Carbonyl Compounds 2.4.2. Reactions of -Trimethylsilylcarbanions with Carbonyl Compounds 2.4.2. Reactions of -Trimethylsilylcarbanions with Carbonyl Compounds 2.4.