北京大学 电分析 课件 elect4a.ppt

恒电流法的电流控制信号(a)电位响应信号(b) Sand 方程： i?1/2 /coxb =0.5nFA(?D)1/2 =85.5nA (D)1/2 Aqueous Phase Organic Phase Aqueous Phase Organic Phase Asymmetric Diffusion Field Chapter Six Kinetics and Transport in Electrode Reactions 电极反应的动力学和传质过程 1.1 Introduction 1.2 The global electrode process: kinetics and transport 1.3 Reversible reactions 1.4 Irreversible reactions 1.5 The general case 1.6 The effect of the electrolyte double layer on electrode kinetics 1.7 Electrode processes involving multiple electron transfer 1.8 Electrode processes involving coupled homogenous reactions 6.1 导言 前面两章分别介