活性炭载钌催化剂在二氧化碳加氢气氛中稳定性研讨.pdfVIP

G042 活性炭载钌催化剂在二氧化碳加氢气氛中稳定性研究 易丽丽 李小年* （浙江工业大学资源与环境催化研究所，绿色合成技术国家重点实验室培育基地，杭州310032 ） 摘 要 本文在对氧化物和活性炭负载钌催化剂的二氧化碳加氢性能研究基础上，考察了二氧化碳和氢气 气氛中活性炭的稳定性。结果表明在钌催化剂作用下的二氧化碳加氢反应中，二氧化碳的转化率和甲烷选 择性都很高，并且，活性炭由于参加了与氢气的甲烷化反应和与二氧化碳的气化反应产生了流失。通过原 位 TG 表征研究了不同气氛、温度和 CO2 含量等条件下催化剂的失重情况。结果表明，活性炭与二氧化碳 的气化反应是一个很显著的反应，但是同时也会因为氢气的存在而受到抑制。催化剂的失重速率随着温度 的升高先增加后减小。失重速率在CO2 : H2 的值为 1:4 时最高。 关键词 Ru/C 二氧化碳加氢 稳定性 中图分类号 STUDY ON THE STABILITY OF CARBON SUPPORT OF RU/C IN CO2 HYDROGENATION Lili YI and Xiaonian LI* (Resources Environment Catalysis Institute of Zhejiang University of Technology, State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Hangzhou 310032) Abstract The stability of carbon support over Ru in the gas of CO and H has been studied on the 2 2 basis of the study on the hydrogenation of CO2 over oxides and active carbon (AC) supported Ru catalysts. The results indicated the high conversion of CO and high selectivity to CH could be 2 4 achieved over Ru in the hydrogenation of CO2 ; The occurrence of methanation of active carbon support with H2 on Ru and the gasification with CO2 will result in the degradation of Ru/AC catalysts in the hydro-process. TG characterizations indicate the gasification of active carbon with CO2 is a significant reaction, but it can be highly restrained in the presence of hydrogen. The carbon loss rate will change with the increase of reaction temperature and the content of CO . 2 Keywords Ru/C, CO2 hydrogenation, Stabili