壳聚糖鄄海藻酸钠吸附剂对电镀废水中CrVI的吸附性能研究-表面技术.PDF

摇摇摇 84 常会摇 壳聚糖鄄海藻酸钠吸附剂对电镀废水中Cr(VI)的吸附性能研究 壳聚糖鄄海藻酸钠吸附剂对电镀废水中Cr(VI)的吸附性能研究 常会 (攀枝花学院,攀枝花617000) 摇 摇 [摘摇 要]摇 以天然壳聚糖(CS)和海藻酸钠(SA)为原料,在CaCl 作用下,制备了壳聚糖鄄海藻酸钠(CS鄄SA) 2 吸附剂。 采用红外光谱仪对CS鄄SA吸附剂官能团进行表征,表明壳聚糖和海藻酸钠之间产生了静电吸引作用。 以含低浓度Cr(VI)的电镀废水为处理对象,考察了CS鄄SA 用量、吸附时间和pH值对CS鄄SA吸附性能的影响,同 时对吸附动力学进行了研究。 结果表明:当pH=6,吸附时间为120 min,CS鄄SA 用量为0.15 g 时,离子去除率最 高,达到了98.86%;吸附动力学最符合拟二级动力学方程。 解吸鄄再生实验表明,CS鄄SA吸附剂可以再生使用。 [关键词]摇 CS鄄SA吸附剂;电镀废水;Cr(VI);吸附性能 [中图分类号]TG174.42 摇 摇 摇 [文献标识码]A 摇 摇 摇 [文章编号]1001鄄3660(2013)05鄄0084鄄05 Study on the Adsorption Property of Chitosan鄄sodium Alginate Absorbent for Cr(VI) in Electroplating Waste Water CHANGHui (Panzhihua University,Panzhihua617000,China) [Abstract]摇 A new kind of chitosan鄄sodium alginate absorbent was prepared using natural products chitosan and sodium alginate as raw material in the presence of CaCl . The functional groups of the CS鄄SA absorbent was characterized by FT鄄IR. 2 The resultsshowthatchitosanandsodiumalginateproduceelectrostaticattraction. Theeffectsof CS鄄SAdosage,adsorptiontime and pH on adsorption property for low concentration Cr(VI) in electroplating wastewater were studied,and corresponding ad鄄 sorption kineticswasinvestigated. Theexperimentalresultsshowthattheadsorptionratecanreaches98.86% undertheoptimal conditions of dosage0.15 g,absorption time 120 min and pH6. The absorption kinetics accordswith the pseudo鄄second鄄order equation. The desorption鄄regeneration experiment reveals that CS鄄SA adsorbent can regenerate and be reused. [Key words]摇 CS鄄SA absorbent;electroplating waste water;Cr(VI);adsorption properties 摇 摇 电镀是主要的材料表面处理技术之一,在国民经 金属离子吸附剂的开发热点[12—13]。 单一吸附剂由于 济中起着举足轻重