碳包覆LiFePO4的制备和性能研讨.pdfVIP

碳包覆LiFePO 的制备和性能研究 4 邱瑞玲，唐致远 （天津大学化工学院，天津300072，中国） 摘要：为提高锂离子电池正极材料LiFePO 的充放电性能,用碳包覆的方法对其进行改性研究。采用高温固相 4 法合成碳包覆LiFePO4 ，用葡萄糖提供碳源，利用X射线衍射（XRD）对样品的晶体结构进行了分析研究，并比 较研究了不同含碳量的样品的电化学性能。结果表明，此种方法制备的LiFePO 为单一相的橄榄石型晶体结构， 4 -1 具有3.4V左右的放电电压平台，结果表明含碳量为6％的材料的放电比容量最高,首次放电比容量达143mAhg , 为理论值的84.2％（理论值为170mAhg-1 ），循环性能及倍率性能最佳。 关键词：锂离子电池；正极材料；碳包覆；LiFePO ；电化学性能 4 The Prepatation and Performance Study of Carbon Coated LiFePO4 Qiu Rui-ling，Tang Zhi-yuan (School of Chemical Engineering and Technology，Tianjin University，Tianjin 300072,China) Abstract: We adopted carbon coated to improve the charge-discharge performance of LiFePO4 as a cathode material in lithium-ion batteries. Carbon coated LiFePO4 were synthesized by solid-state reaction and glucose is the source of carbon.The crystalline structures of the samples were investigationed by X-ray diffraction.The effect of carbon content on the electrochemical performance was also studied.The results showed that carbon coated LiFePO4 were simple pure olive-type phase,and exhibit a 3.4V discharge voltage plateau.The material synthesized with 6% carbon has the best discharge capacity, circle performance and rate performance. And the first discharge capacity is as high as 143mAhg-1 that is 84.2% of the theoretical one( theoretical capacity: -1). 170mAhg Key words: Li-ion battery;