液相法结合冷冻干燥技术制备Li4SiO4材料及其高温二氧化碳吸收性能.pdfVIP

Journal of Advances in Physical Chemistry 物理化学进展, 2015, 4, 77-83 Published Online May 2015 in Hans. /journal/japc /10.12677/japc.2015.42010 A Liquid Phase Method Combined with Freeze-Drying Technique to Lithium Silicate Materials and Their Carbon Dioxide Absorption Properties at High Temperatures Yi Tong, Xueqin Huang, Chunhui Xu, Qiang Xiao, Yijun Zhong, Weidong Zhu Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua Zhejiang Email: 824838212@ th th th Received: May 9 , 2015; accepted: May 25 , 2015; published: May 29 , 2015 Copyright © 2015 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Abstract A liquid phase method combined with the freeze-drying technique was developed to synthesize Li SiO materials using LiOH∙H O, LiNO , Li CO and silica sol as the lithium and silicon sources, 4 4 2 3 2 3 respectively. The weight loss behaviors of the prepared Li4SiO4 precursors were investigated by the thermal gravimetric analysis (TGA). The structure and morphology of the prepared Li4SiO4 materials were characterized by XRD and SEM, respectively. The CO2 absorption properties of prepared Li4SiO4 were investigated by thermal gravimetric analysis (TGA). The results show that the Li SiO material prepared using LiOHH O as the lithium source presents the best CO absorp- 4 4 2