蛋白质污染的PNIPAAm+接枝聚乙烯多孔膜的变温清洗行为研究.pdfVIP

H014 蛋白质污染的 PNIPAAm 接枝聚乙烯多孔膜的变温清洗行 1 为 1 1 *2 郭浩飞 黄健 王晓琳 1 2 （南京工业大学材料学院，南京210009； 清华大学化工系，北京100084） 摘 要 以BSA 作为污染蛋白质，对 PNIPAAm 接枝的聚乙烯多孔膜作了模拟污染。利用 PNIPAAm 接枝 链的不连续的亲水性/疏水性转变的性质，用流量和流动电位测试方法，研究了变温清洗工艺对污染接枝 膜的清洗效果。实验发现，以水为清洗介质，用变温清洗工艺，可以恢复接枝膜的流量值。另外，裸露的 载体膜表面也有蛋白质吸附现象，以稀碱溶液为清洗介质，同样用变温清洗工艺，可以恢复接枝膜的流动 电位值，最终得到了较好的清洗效果。结果表明，接枝链的亲水性是实现以上清洗效果的关键。 关键词 膜污染 聚（N-异丙基丙烯酰胺） 温敏性 亲水性 流量 流动电位 CLEANING STUDY OF A PROTEIN-FOULED PNIPAAM GRAFTED POROUS PE MEMBRANE BY THE REVERSIBLE TEMPERATURE-CHANGE CLEANING METHOD 1 1 2 GUO Haofei , HUANG Jian and WANG Xiaolin 1 ( College of Material Science and Engineering, Nanjing University of Technology, Nanjing 210009; 2Department of Chemical Engineering, Tsinghua University, Beijing 100084) Abstract Based on the reversible hydrophilicity-hydrophobicity change of Poly (N-isopropylacrylamide) (PNIPAAm), the cleaning behavior of a PNIPAAm grafted PE porous membrane fouled by BSA was studied by the reversible temperature-change cleaning method between the LCST, and was characterized by both the water flux measurement and the streaming potential measurement. The recovered water flux by the simple temperature-change cleaning of water confirmed that most of the proteins adsorbed on the membrane surface had been eluted. However, the streaming potential analysis showed that the protein adsorption occurring on the naked substrate membrane surface without