节能型热法磷酸燃磷塔传热传质的三维数值模拟研究.pdfVIP

节能型热法磷酸燃磷塔传热传质的三维数值模拟 蒋家羚，刘宝庆 （浙江大学化学工程与生物工程学系，浙江杭州 310027 ） 摘要： 针对热法磷酸生产中一方面要求外部供热，另一方面又浪费自身燃烧热的现状，提出能回 收余热的新工艺，开发成功膜式水冷壁结构新型燃磷塔。建立了考虑新型燃磷塔内流动、燃烧、 传热过程的三维数学模型，通过数值模拟得到塔内湍流场、温度场和组分浓度场的分布。模拟结 果显示，燃磷塔内存在明显的涡流射流结构，磷的燃烧主要在喷磷枪雾化角范围内，塔内最高燃 烧温度约为1790K，出现在喷磷枪轴线上偏离燃磷塔中心的一侧。烟气出口温度约为970K，与测 量值符合较好。 关键词： 燃磷塔；节能；数学模型；数值模拟 中图分类号：TQ126.3 ，TK11+5 文献标识码：A Simulation of mass and heat transfer in new phosphoric tower with circular water wall JIANG Jialing ，LIU Baoqing (Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, Zhejiang, China) Abstract: To avoid the energy waste in the production of furnace grade phosphoric acid, a new phosphoric tower with circular water wall was designed, which could recover waste heat to produce superheated steam with the help of drum. A three dimensional mathematical model of phosphorus combustion in the new phosphoric tower was developed by incorporating k −ε turbulence model, eddy dissipation turbulent combustion model and P-1 radiation heat transfer model. The streamline field distribution, temperature distribution and species concentration distribution were predicted by numerical simulation. The results showed that phosphorus combustion mainly took place in the injection zone of atomized phosphorus; the maximum combustion temperature and exit temperature were 1790k and 970k respectively which conformed well to practical data. Key words: phosphoric tower ；energy conservation ；mathematical model ；numerical simulation 引 言 1 改进的热法磷酸生产工艺与装备[4] 目前的热法磷酸生产存在着能源需求 基本目标：回收磷的燃烧热用于固态黄 与浪费的不合理现象，一方面需要配置专用 磷的熔化，实现能源综合利用。 燃煤锅炉供应蒸汽熔融固态黄磷，另一方面