褶皱石墨烯材料的制备及其电化学性能研究.PDFVIP

中国科技论文在线 褶皱石墨烯材料的制备及其电化学性能研 究 # 盛利志，魏彤，范壮军** 5 （哈尔滨工程大学，材料科学与化学工程学院，哈尔滨150001） 摘要：本文通过改良的Hummers 方法制备出二氧化锰掺杂氧化石墨烯，随后经过热处理再将 二氧化锰除去制备出具有丰富含氧官能团的褶皱石墨烯材料。采用X 射线衍射仪、X 射线光 电子能谱仪和扫描电子显微镜表征了产物的组成、形貌和结构。循环伏安、恒电流充放电等 10 测试表明：褶皱石墨烯材料具有很好的电容性能，在2mV/s 的扫速下，比电容高达335F/g， 且在200mV/s 的扫速下循环 10000 次后，比电容仍能保持94.6%。该电极材料在超级电容 器上具有较好的应用前景。 关键词：超级电容器；石墨烯；电容性能。 中图分类号：TB32 15 Preparation and electrochemical performance of wrinkled graphene Sheng Lizhi, Wei Tong, Fan Zhuangjun (Harbin Engineering University, college of materials science and chemical engineering, 150001) 20 Abstract : In this paper, MnO2/Graphite oxide nanocomposites were first prepared by using the modified Hummers method. Following this, the wrinkled graphene were prepared by thermal-treatment of MnO2/Graphite oxide and remove MnO2. The component, structure and morphology of as-prepared materials were investigated by X-ray diffraction(XRD), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). And the electrochemical performances were investigated by CV 25 and constant current charge/dischargetechniques. The results showed that the specific capacitance of wrinkled graphenes as singleelectrode is up to 335F/g at the scan rate of 2mV/s and remains at about 94.6% of the initial value after 10000 cycles under the scan rate of 200mV/s, which indicates that this material has highly promising potential for supercapacitor . Key words: Supercapacitor; Graphene;Capacitance performance 30 0 引言