一种高强度、低成本自硬呋喃树脂制备工艺的研究.pdfVIP

2013 中国铸造活动周论文集 一种高强度、低成本自硬呋喃树脂制备工艺的研究 伟华，刘诗阳，李英民 （沈阳工业大学材料科学与工程学院，辽宁沈阳110870） 摘要：本文以试验制备一种高强度、低成本自硬呋喃树脂为目标，对影响呋喃树脂性能的主要因素进 行了分析，采用正交试验方法对一种含氮量3%脲醛呋喃树脂的合成工艺进行优化，确定了影响因素 及水平，获得了较高的强度。在此基础上，采用多元醇A 、甲醇、木糖醇母液、多元醇B、乙醇等材料对 糠醇进行了部分替代，复合替代比例达到树脂总量的20% ，取得了较好的试验结果，最后通过采用红 外光谱对其替代机理进行了表征及分析。 关键词：呋喃树脂；工艺优化；糠醇替代；替代机理 A Research on Synthesis of a No-bake Furan Resin with a High Strength and a Low Cost LIU Wei-hua ，LIU Shi-yang ，LI Ying-min (School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, Liaoning) Abstract: The synthesis of a no-bake furan resin with a high strength and a low cost was researched in this paper. Through the analysis of main effect factors on the strength of furan resin, a orthogonal experiment was done to optimize synthesis of urea-formaldehyde furan resin with 3% nitrogen, the key influence factors and their levels was confirmed and a high strength was obtained. Then, some active substitute materials such as polyols A agent, methyl alcohol, mother liquid of xylitol, polyols B agent and ethanol were used for partly substitution of furfural alcohol which is the main material of furan resin. And a better combination of the substitute materials was got with a high strength and the overall proportion of substitute materials is 20% to the resin. At last, the substitution mechanism on furan resin was characterized and analyzed by IR. Key words: furan resin; synthesis optimization; substitute of furfuryl alcohol; substitution mechanism 1 前言 自硬呋喃树脂砂工艺具有室温下自行硬化、造型制芯强度高、旧砂易回用、生产铸件尺寸精度高、 劳动强度低等优点，目前在铸造生产中的应用越来越广泛，也对呋喃树脂的质量提出越来越高的要求 [1-2] 。合成呋喃树脂的主要原材料为糠醇，对于一些牌号的呋喃树脂，其用量可高达到85% ～90% ，而 近年来，其价格一直高居不下。因此，研发高强度、低成本自硬呋喃树脂很有意义。 本文通过正交试验，对含氮量3%的脲醛呋喃树脂的合成工艺进行了优化，确定了关键的影响因 素及水平