多孔改性淀粉的合成及对铜离子的捕集性能研究.pdfVIP

多孔改性淀粉的合成及对铜离子的捕集性能 * 江志平，相波，李义久，程如梅 （同济大学化学系，200092，上海） 摘要：为了增加改性淀粉类吸附剂对重金属的捕集容量，文章采用酶解法制备了多孔改性淀 粉。比原淀粉相比，所制备多孔淀粉比表面积增大了 132.5%。酶解后多孔淀粉经交联、醚 化、胺化，以及与CS 加成反应，制备出二硫代氨基甲酸基多孔改性淀粉（DTCPS），与原 2 淀粉直接改性得到的二硫代氨基甲酸基改性淀粉（DTCS）相比，在pH 值为2.0 时， DTCPS 2+ -1 2+ -1 对Cu 的捕集量明显增加达到75.2mg·L 。初始Cu 浓度为0～70 mg·L 范围内，0.05g 2+ -1 DTCPS 均能使50ml 水溶液中Cu 残留浓度小于0.12 mg·L 。 关键词：多孔淀粉；二硫代氨基甲酸基；吸附；铜离子 Synthesis of Porous Modified Starch and Its Chelating Effects on Copper（Ⅱ） Ion Zhi-ping JIANG ，Bo XIANG ，Yi-Jiu LI ， Ru-Mei CHENG （Department of Chemistry, Tongji University, 200092, Shanghai） Abstract One modified porous starch was prepared by enzymolysis method in order to increase the chelating capacity of modified starchy adsorbent. The surface area of porous strach was increased 132.5% compared with native starch. Through crosslink, etheration, amination and addition reaction with CS2 , dithiocarbamate modified porous starch（DTCPS） was prepared with the porous starch that was prepared by enzymolysis. Compared with dithiocarbamate modified starch which was prepared by native starch directly, the chelating capacity of DTCPS was -1 increased to 75.2mg·L obviously when pH was 2.0. When the initial concentration of copper ion -1 ranged from 0 to 70 mg·L , 0.05g DTCPS can make 50ml aqueous solution at low residue -1 concentration that the copper concentration was less than 0.12 mg·L . Keywords Porous Stach; dithiocarbamate; absorption; copper ion