上海工业区大气颗粒物中硫的化学形态和分布 Speciation and distribution of sulfur in size-fractionated particulate matters in industrial district of Shanghai.pdfVIP
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上海工业区大气颗粒物中硫的化学形态和分布 Speciation and distribution of sulfur in size-fractionated particulate matters in industrial district of Shanghai
中国环境科学2009,29(3):231~236 ChinaEnvironmentalScience
上海工业区大气颗粒物中硫的化学形态和分布
包良满1”,张元勋1,李晓林1,李燕p,刘 卫1,赵屹东3,马陈燕3,韩勇3(1冲国科学院上海应用物理
硫酸盐形式存在;超细颗粒物中除了硫酸盐硫之外,一部分硫以低价的还原态形式存在,可能的化学形态为金属硫化物、噻吩类有机硫化
物.细粒子中硫的质量浓度高于粗颗粒,约70%的硫分布在细粒子中.硫的质量浓度呈多模态分布.工业区的超细颗粒物峰值出现在
硫的分布特性,工业区颗粒物中硫的来源有海盐源的贡献,而郊区较少受海洋源的影响.
关键词:大气颗粒物;硫;粒径分布;形态
中图分类号:X513,0434.19文献标识码:A 文章编号:1000—6923(2009)03—0231—06
anddistributionofsulfurinsize—fractionatedmattersin districtof
Speciafion particulate industrial
Yuan—xunl,LIXiao-linl,LIYanl4,LIUWeil,ZHAO MA 3,HAN
Liang—manl,2,ZHANG Yi—don93Chen.yan Yon93.
Institute
(1.ShanghaiofAppliedPhysics,ChineseAcademyofSciences,Shanghai
oftheChinese of of of
100049,China;3.Institute
AcademySciences,Beijing HighEnergyPhysics,ChineseAcademy
1 Environmental 1-236
0049,China).ChinaScience,2009,29(3):23
Sciences,Beijing
Abstract:Airbornewerecollectedatindustrialdistrictandsuburbanareain at Dekati
particles Shanghaiusing3一stage
low asize from28nmto radiation of
pressureimpactorcoveringrange 9.92pm.SynchrotrontechniquesX—ray
structure fluorescence wasthe
near-edge specgoscopy(XANES)andX—ray spectrometry(XRF)wereemployed.Sulfate
dominantformofsulfurinbothcoarseandfine addition.asmallamountofsulfurwasalso asmetal
particles.In present
sulfideand inultrafine of in was thanthatin
forms concentrationsulfurfine
thiophenic particles.Mass particlehigher
coarse itconstitutedto70%oft
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