四正丙基溴化铵的合成研究-中国科技论文在线.PDFVIP

中国科技论文在线 四正丙基溴化铵的合成研究 秦瑞霞，刘仕伟** 266000 5 摘要 ： 1- 3 MPa N2 30 mL 1:5 1-n( ) : n(1-) = 1.0 : 1.2120oC 14 h84.12%98.92%1H NMR 10 13C NMR FT-IR 关键词：1- 中图分类号：TQ 016 Study on Synthesis of Tetraproply Ammonium Bromide 15 QIN Ruixia, LIU Shiwei (Qingdao University of Science and Technology,School of Chemical Engineering,Qingdao 266000) Abstract: In this work, it reported one step synthesis of tetraproply ammonium bromide under pressure using trinpropylamine and 1-bromopropane as raw materials. The effects of solvent selection and 20 dosage, reactant proportion, reaction temperature, reaction time and the effect of the reaction to determine the optimal synthesis conditions. Under optimal conditions : filling the 3 MPa N2, the amount of solvent ethyl acetate was 30 mL, a mixture of the solvent acetone and 1-bromopropane is 1:5, n(trinpropylamine) : n(1-bromopropane) = 1.0 : 1.2, reaction temperature 120oC, reaction time 14 h. Under the condition of the yield of n-propyl ammonium bromide was 84.12% and the purity was 25 98.92%. The synthesized samples were characterized by FT-IR and NMR. The results showed that the synthesized samples were the ta rget compounds. Key words: tetraproply ammoni