F型动力电池的研制研究.pdf

F型动力电池的研制 唐致远，王倩 （天津大学化工学院应用化学系，天津300072） 摘要：采用传统的生产工艺研制了LiMn O F型锂离子动力电池。为提高电池的大电流放电能力，对原料配方 2 4 进行改进，用电化学工作站，充放电测试仪，交流内阻仪测试了电池的交流阻抗性能，倍率放电特性，可得 出结论：增加导电剂的含量可提高电池的倍率放电性能，导电剂含量7%的电池1C、2C的倍率放电性能远远优 于导电剂含量 5%的电池，前者 2C循环 50 次后容量保持率为 83.13%,后者 50 次循环时容量降到起始容量的 92.35%左右。随着导电剂含量的增加，电极材料之间的导电性提高，倍率放电性能得到改善。 关键词：F型动力电池；配比；倍率性能； The Research Of F-type Power Battery Tang Zhi-yuan, Wang Qian （School of Chemical Engineering and Technology，Tianjin University，Tianjin 300072，China) Abstract:LiMn O /C dynamical Lithium–ion batteries of F-type were manufactured 2 4 through presently traditional technics. In order to improve dynamical performance the raw material proportion and electrode structure were amended, The electrochemical impedance spectroscopy (EIS),rate discharge performance were tested by electrochemical working station ,charge-discharge instrument and AC-resistance instrument. It was concluded that The rate discharge performance was improved with electric matter increasing. The 1C and 2C rate discharge performance of the batteries containing 7% electric matter was very better than those containing 5% electric matter and the former capacity maintenance ratio is 83.13% after 50 cycles of 2C,while the latter capacity maintenance ratio is 92.35% after 50 cycles of 2C.The reason is that the conductivity is improved with electric matter increasing through EIS tests. Key words: F-type dynamical lithium-ion batteries ；proportion ；rate discharge performance ； 上个世纪80年代以来，随着全球经济的稳步发展，汽车的产量和保有量急剧增加。这些 燃油汽车所排放的废气造成空气质量日趋恶化。环境问题，特别是大气环境污染问题，已引 起世界各国，尤其是发达国家的普遍关注。同时，目前世界石油资源日趋紧张，石油价格始 终居高不下。因此，各国政府和各大汽车企业都正在加紧开发无排放或低排放、低油耗的清 收稿日期：2006-8-22 作者简介：唐致远（1946－），男（汉族），安徽定远