淀粉模板法合成介孔ZSM5分子筛研究.pdf

石油学报(石油加工) 2008年10月 ACTAPETROl。ElSINICA(PETROLEUMPROCESSINGSECTION) 增刊 文章编号：1001—8719(2008)增刊一0124—03 淀粉模板法合成介孔ZSM-5分子筛 刘志成，孔德金，王仰东，谢在库 (中国石化上海石油化工研究院，上海201208) 摘要：采用淀粉为模板剂合成了一种新的介孔ZSM一5分子筛，并用XRD、SEM、TEM、低温氮气吸附等手段对 其物相和孔结构进行了表征。结果表明。介孔ZSM一5分子筛的晶粒内包含晶内介孔，且介孔孔容随合成中淀粉 模板剂比例的增加而增大。将该分子筛用于超l临界甲苯歧化反应，失活速率慢于常规的ZSM一5分子筛．其原因 可能是因为介孔分子筛的扩散性能提高所致。 关键词：ZSM一5；介孔分子筛；淀粉；甲苯歧化 0782．1 中图分类号：0613．72，0741．4；0636．1l文献标识码：A THEMESoPOROUSZSM-5SYNTHEIZEDWITHSTARCHC0卜TEMPLATE LIU in，WANG Zai—ku Zhi—cheng．KONGDe-j Yang—dung，XIE ImtitutePetrochemical 201208，China) (Shun·西aiResearchof Technology，SINOPEC，Shanghai newkindof ZSM一5was starchAS Abstract：A mesoporous hydrothermalsynthesizedbyusing co-template．The and structureofthe ZSM-5werecharacterizedvariousmeasurements，such physicalpropertiespore mesoporous by as that wasa sumof XRD，SEM，TEM，N2measurement，et．。whichdemonstratedthere considerable adsorption insidethezeolite their volumewouldincreaseastheamountofstarch mesopores erystallites，andmesopore inthe mixturewas onthereactionof added reaction increased．In studies co-template addition，catalysis supercritical toluene revealedthatthe ZSM一5 had lowerdeactivateratethanthe disproportionationmesoporouscatalystrelatively conventionalZSM-5 maybeduetOtheimprovementofthediffusionwithinthe zeolite． catalyst，which meaoporus Keywords：ZSM-5；mesoporouszeolite；starch；toluenedisproportionation