双季戊四醇二亚磷酸酯阻燃剂的合成.pdfVIP

10 2 ( ) V l. 10 N . 2 2010 6 JOURNAL OF NAN JING NORMAL UNIVERSITY( ENG INEER ING AND TECHNOLOGY ED IT ION) Jun, 2010 双季戊四醇二亚磷酸酯阻燃剂的合成 周 浩, 王 丹, 张士磊, 职慧珍, 杨锦飞 ( , 210097) [ ] (DPE)( TPP), , . , : , 1% , n ( P( OPh) ) n ( C H O ) 2061, 100 ~ 110 , 3 10 22 7 10 h, 863% . . [ ] , , , , [ ] TQ265. 1 [] A [] 2010) Synthesis of F ire Retardants of D ipentaerythritolD iphosphonate Ester Z hou Hao, W ang Dan, Z hang Sh ile,i Z h i Hu izhen, Yang J infe i ( Sch l f Ch em istry and Envir nm ental Science, Nanjing N rm alUn iversity, N anjing 210097, Ch ina) Abstract: Dipentaerythrit l cyclic ph sph nate ester was synthesized fr m d ipentaerythrit l(TPE ) and triphenylph s ph ite(TPP) in the presence f s d ium hydr x ide catalyst by a step f ester exchange reacti n. The effects f pr cess pa rameters, such as m lar rati, reacti n temperature, reacti n tmi e and cataly st n the y ield w ere studied respectively fr m rth g nal expermi ents. The su itab le synthesis c nditi ns were defined as f ll w s: s dium hydr x ide is the suitable catalyst, its d sage is 1% f the am unt f all reactan t, them lar rati f triphenylph sph ite and dipentaerythrit l is 2. 061, the reacti n tem perature is 100 ~ 110 , and the reacti n tmi e is 10 h urs. On the ab ve c nd iti ns, the syn thesis pr ductivity is 86. 3% . The structure f the pr duct was c nfirm ed by IR and EA respectively. K ey words: d ipentaerythrit l, triphenylph sph ite, ester exchange, diph sph nate, fire retardant [ 1] , ( PE) , . 1960 [ 2] , V erkade , , . Charles F Baranau lkas( PE)( TPE) ( TPP)