柴油超深度脱硫催化剂Co-Mo-Ni-W Al2O3的制备及表征 毕业设计.docVIP

柴油超深度脱硫催化剂Co-Mo-Ni-W/Al2O3的制备及表征 应用化学班 指导老师：2007年6月8日 摘要 随着世界性的原油质量变差变重，导致一次加工后的柴油质量很差，油品的硫含量、氮含量及金属含量很大，且油品偏重。为了得到符合环境规定的合格柴油，必需对柴油进行加氢精制。而加氢精制的关键在于选择合适的催化剂。由于不同金属组分的加氢精制活性不同，试验选择研制Co-Mo-Ni-W/Al2O3四个金属活性组分催化剂。试验考察了不同载体配方对载体物理性质的影响，考察了不同浸渍液配方对催化剂物理性质的影响，考察了不同焙烧温度对催化剂物理性质的影响，考察了活性组分在催化剂表面的分散状况，优选出加氢精制活性较好的A2催化剂。将其与参比剂一及参比剂二比较，可以看出A2较好的加氢精制能力，A2与两个参比催化剂性能相当。 关键词：柴油 ；加氢精制；催化剂；制备 ABSTRACT In the recent years, crude oil is becoming heavier and the quality of it is deteriorating. As a result of it ,the quality of primary processing diesel oil is becoming worse .The oil has a high content of sulfur ,nitrogen ,and metallic component ,and also the oil’s density is high. In order to produce diesel oil which can meet the requirement of protecting environment , there is a need to hydrotreat the diesel oil. To hydrotreat the diesel oil , the hydrotreating catalyst is most important. Because different metallic component has different activity in the hydrotreating process, writer decide to make a catalyst contain four metallic component -- Co-Mo-Ni-W/Al2O3.In the experiment , the impact of vector’s raw material on the vector’s physical character is tested, the impact of impregnating solution’s raw material on the catalyst’s physical character is tested, the impact of roasting temperature on the catalyst’s physical character is tested, the disperse state of metallic component on the catalyst is tested. By these tests , A2 catalyst is selected because it is more active than other catalyst in the hydrotreating process. Comparing the product oil of A2 and comparing catalyst comparison 1 and comparison 2, A2 is confirmed that it has a good performance in the hydrotreating process ,and its performance can reach the level of comparison1 and comparison 2. Keywords:diesel;hydrotreating;catalyst; impregnating solution 目录 第1章 前言 1 1.1 研究的背景和意义 1 1.2 国内外柴油加氢精制催化剂的研究现状 5 1.3 柴油加氢脱硫机理 8 1.3.1 噻吩脱硫机理 9 1.3.2 二苯丙噻吩的加氢脱硫机理 9 1.3.3 4-MDBT加氢脱硫机理 10 1.3.4 4,6－二甲基二苯并噻吩加氢脱硫机理 10 1.4 柴油加氢精制催化剂的研究