酚醛树脂废水来源及水质特性.docVIP

摘 要 酚醛树脂是由酚类(如苯酚、甲酚、二甲酚和壬酚等)和醛类(如甲醛、乙醛和糖醛等)在酸或碱的催化作用下合成的, ,并且还含有大量醇类、酸类等有毒物 ,处理难度大高浓度含酚醛废水需采用萃取、化学氧化、吸附、缩合等预处理降低有毒有害物的毒性和浓度后才可生化处理。 酚醛树脂 Abstract The phenolic resin is a phenol (such as phenol, cresol, xylenol, and nonyl phenol, etc.) and aldehydes (such as formaldehyde, acetaldehyde and furfural, etc.) in acid or alkaline catalyst synthesis, and its production Process wastewater containing high concentrations of phenols, aldehydes, and also contains large amounts of alcohols, acids and other toxic substances, treatment is difficult. Phenolic wastewater containing high concentration requires the use of extraction, chemical oxidation, adsorption, condensation preconditioning decrease the toxicity of toxic and hazardous compounds, and only after the concentration of biological treatment. The trials for the treatment of wastewater plant in Jiaozuo City, a modified phenolic resin adhesive production of wastewater, the production of emissions 2 t / d or so of wastewater. Experiment, alkaline condensation experiment, in which the condensation point one step condensation reaction and two-step condensation reaction. Orthogonal factors by looking for and value of each factor level of response, and ultimately determine the level of the four factors and three orthogonal, a total of 9 groups to do experiments. Water sample and test water samples after the COD value of the condensation, the concentration of formaldehyde, phenol concentration, PH value and other indicators. two-step condensation We only got the first step of the reaction, COD removal rate is not very high, the highest is 41.2%, removal rate of formaldehyde at 30-40%, and phenol removal Between 40-60%. . By contrast, after one step condensation reaction and two-step condensation reaction the pre-effect, come to step condensation reaction to the more obvious the removal of the three indexes, so in later experiments, select the step response on formaldehyde Follow-up treatment and phenol.  Key words: P