Chapter 5 The Schrodinger equation in three dimensions 量子力学英文教案课件.pptVIP

Chapter 5 The Schrodinger equation in three dimensions The Schrodinger Equation with a Central Potential Hydrogen atom §1 The Schrodinger Equation with a Central Potential The Schrodinger Equation with a Central Potential The solution of Schrodinger equation Wave function conditions Home works Chapter 6 P131: 2, §2 Hydrogen atom Two–body problem The energy levels and wave function The hydrogen-like atoms The hydrogen-like atoms Home works Chapter 6 P131: 6, 7 University of Electronic Science and Technology of China 2005-3-1 Prof. Zhang Xiaoxia? * §1 §2 back The Schrodinger equation with a central potential The solution of Schrodinger equation Wave function conditions Normalizable conditions Brief summery back Hamilton The eigenvalue equation V=-Ze2/r The Coulomb Potential ? x z spherical coordinates r ? y Where L2 ： separation of variables ψ(r,θ, ?) = R(r) Ylm(θ,?) Let L2 Ylm =?(?+1) ?2 Ylm R(r) = u(r) / r ： Let E 0 ： Let ρ→∞ A= 0 ? ? ?2 We can find a solution in terms of the power series Let The wave function finite when r → 0 , R = u / r → is finite Into equation ν=ν-1: separation of ν= 0 ： ν‘ ν： [s(s-1)-?(? +1)]b0 = 0 → s(s-1)- ?(? +1) = 0 S = - ? is not for s ≥1 ，Delete。 s = ?+1 The coefficients ： [(ν+ s + 1)(ν+ s )- ?(? + 1)]bν+1+(β-ν-s)bν = 0 A recursion relation for bν s = ?+1 e ρ f (ρ) e ρas some as f(ρ) 1.A single valued 2.Be finite 3.Be continuous νmax = nr Let nr+ ? + 1 So recursion relation Using the definition of ? ? En 0 β= n into recursion relation ： Use recursion relation b1, b2, ..., bn-?-1 b0 ： the associated Laguerre polynomial The total wave function ： The radial wave function ： The radial wave function the Bohr radius Normalizable conditions for spherical function： Normalizable conditions The first few of the radial wave function R n l are： The eigenvalue and the eigenfunctions Brief sum