乙基环己烷催化裂解制低碳烯烃反应动力学-化工学报.PDF

第 67 卷 第 8 期 化 工 学 报 Vol.67 No.8 2016 年 8 月 CIESC Journal August 2016 DOI ：10.11949/j.issn.0438-1157 乙基环己烷催化裂解制低碳烯烃反应动力学 张睿，郭少鹏，刘贵丽，刘海燕，刘植昌，孟祥海 （中国石油大学（北京）重质油国家重点实验室，北京 102249 ） 摘要：利用小型固定床实验装置研究了乙基环己烷在基于ZSM-5 分子筛介孔催化剂上的裂解性能，发现乙基环己 烷具有较好的裂解性能，原料转化率在 80% 以上，乙丙烯收率（质量分数）可达41% ，低碳烯烃收率（质量分数） 接近 50%，液体产物主要是苯、甲苯、二甲苯等芳香烃。同时考虑乙基环己烷催化裂解过程中的热反应与催化反 应，建立了包含 14 个反应的动力学模型。基于 4 个反应温度下的裂解实验数据，求取了反应动力学模型的参数。 求得的表观活化能均在 90 kJ ·mol−1 以下，主要组分收率的模型预测值与实验值的平均相对误差不高于 10%。 关键词：反应动力学；催化；固定床；乙基环己烷；乙烯；丙烯 中图分类号：TE 624.4 文献标志码：A 文章编号：0438—1157 （2016 ）08—3422—07 Reaction kinetics of ethylcyclohexane catalytic pyrolysis for production of light olefins ZHANG Rui, GUO Shaopeng, LIU Guili, LIU Haiyan, LIU Zhichang, MENG Xianghai (State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China) Abstract: The cracking performance of ethylcyclohexane on a mesoporous catalyst based on ZSM-5 molecular sieve was investigated in an apparatus with a fixed-bed reactor. The results showed that ethylcyclohexane had good cracking performance, the conversion was above 80%, the yield of ethylene and propylene reached 41% (mass), the yield of total light olefins was near 50% (mass), and the main components of liquid products were benzene, toluene and xylene. As reaction temperature increased, the yield of ethylene increased monotonously, and those of propylene and butene showed maxima. With the considera