中孔分子筛MCM-41对镉离子吸附性能研究.doc

中孔分子筛MCM-41对镉离子吸附性能研究 学 生： 指导教师： 摘 要： 采用十六烷基三甲基溴化铵(CTAB)表面活性剂作模板，正硅酸乙脂(TEOS)为硅源，在不同时间内不同的晶化条件合成了具有中孔分子筛MCM-41。通过X射线衍射（XRD）对样品进行了表征，讨论了不同的晶化条件对中孔分子筛的晶体结构的影响。 选择合成样品中结构有序性高的中孔分子筛MCM-41吸附溶液中的Cd2+，用原子分光光度计测定吸附后Cd2+的浓度，探讨了分子筛用量、不同PH值、不同反应时间对分子筛吸附Cd2+的影响。 实验结果表明：当分子筛用量增大，其吸附率不断提高；当分子筛加入量达到平衡所需量以后，继续增大用量会使平衡吸附量降低；当溶液pH值从4增加到8时，分子筛对Cd2+的吸附量和吸附率随着pH值增大而增加，说明在碱性条件下，有利于提高MCM-41材料对Cd2+的吸附；当吸附时间从30 min增加到40 min时，分子筛对Cd2+的吸附量和吸附率随着反应时间增加而增加，但继续增加时间，分子筛对Cd2+的吸附量和吸附率并无明显变化，说明吸附时间大于40 min后，时间对吸附效果的影响不明显。 关键词： 中孔分子筛； MCM-41； 吸附 ；镉 Study on Adsorption of Cadmium(Ⅱ) Ion onto Mesoporous Molecular Sieves MCM-41 Undergraduate: Zhang Weiwei Supervisor: Li Hualan Abstract: Using cetyltrimethylammonium bromide (CTAB) surfactant as template, tetraethyl orthosilicate (TEOS) as silica source, molecular sieve MCM-41 was synthesized at different time and different crystallization condition. The synthesized samples were characterized by X-ray diffraction (XRD) and the effect of crystallization condition on the mesoporous molecular sieve crystal structure were discussed. The highly orderd samples were selected to absorb the Cd2+ solution. The amount of Cd2+ absorbed onto MCM-41 were determined by Fire Atomic Absorption Spectrophotomere (FAAS). The effect of amount of the sieves, the different pH valunes and the different reaction time on the MCM-41 adsorption of Cd2+ were discussed. The results show that the adsorption ration increased with increasing the amount of MCM-41. But when the amount of the MCM-41 added beyond the balanced amount, the equilibrium adsorption capality decreased. When the pH of the solution increased from 4 to 8, the ration of MCM-41 adsorption increased. It suggested that alkaline condition could help improve the adsorption capity. When the adsorption time increased from 30 min to 40 min, the adsorption amount and ration of MCM-41 increased. But the adsorption amount and ration didn’t changed when increasing more time. It suggessted when