氨丙基三甲氧基硅烷膜的结构.PDFVIP

2003 61 Vol. 61, 2003 10 , 1550~ 1555 ACTA CHIMICA SINICA No. 10, 1550~ 1555 - , a a b , b 顾仁敖 陈 惠 刘国坤 任 斌 ( a 215006) ( b 361005) - ( -APS) . X ( XPS) , , . ( SERS) , , , , ; , X . ( AFM) . - , X , , Study on Films of Organofunctional Silanes on Transition Metal Surfaces The Structure of -Aminopropyltrimethoxysilane Films on Nickel Electrodes , a a b , b GU, R n-Ao CHEN, Hui LIU, Guo-Kun REN, Bin a ( Department of Chemistry, Suzhou University, Suzhou215006) b ( StateKey Laboratoryf or hysical Chemistry of Solid Sufr aces, Department of Chemistry, Xiamen University, Xiamen361005) Abstract In th pr s nt pap r, w pr par d th -aminopropyltrim thoxysilan ( -APS) films on nick l l ctrod surfac s and studi d th ir formation and structur . XPS r sults of th films of th organofunctional silan s modifi d nick l l ctrod s show th pr s nc of nitrog n and silicon binding n rgy p aks indicating th pr s nc of -APS on th m tal surfac . Th r sults also indicat that th amin is pr s nt d in s v ral diff r nt stat s, including th fr amin and th protonat d on . Th pot ntial-d p nd nt Raman sp ctra gav pl nty of information of -APS/ m tal int rfac , th silanol and amino groups adsorb d comp titiv ly on th nick l surfac s. Whil th appli d pot ntial was chang d n gativ ly from op n circuit pot ntial, th p