Influences of surface coated fulvic and humic acids on the adsorption of metal cations to SiO2 nanoparticles英文文献.pdfVIP

Colloids and Surfaces A: Physicochem. Eng. Aspects 389 (2011) 27–32 Contents lists available at SciVerse ScienceDirect Colloids and Surfaces A: Physicochemical and Engineering Aspects j o u r n a l h o m ep a g e : w w w. elsev /locate/cols urfa Influences of surface-coated fulvic and humic acids on the adsorption of metal cations to SiO2 nanoparticles Liang Liang a , Jitao Lv a , Lei Luo a , Jing Zhang b , Shuzhen Zhang a,∗ a State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Centerfor Eco-Environmental Sciences, the Chinese Academy of Sciences, Beijing 100085, China b State Key Laboratory of Synchrotron Radiation, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100039, China a r t i c l e i n f o a b s t r a c t Article history: Humic substances such as fulvic acid (FA) and humic acid (HA) exist universally in the environment and Received 20 July 2011 play an important role in the interfacial reactions of contaminants. In this study, influences of surface- Received in revised form 31 August 2011 coated FA and HA on the adsorption of metal cations of Cu(II), Pb(II) and Zn(II) on SiO2 nanoparticles Accepted 1 September 2011 (nano-SiO2 , 20 nm) were investigated. The results showed that nano-SiO2 had high adsorption capacities Available online 8 September 2011 for the metal cations following the sequence of Pb(II) Cu(II) Zn(II), irrespective of coating with FA or