不饱和聚酯合成及表征毕业论文.docxVIP

不饱和聚酯的合成及表征 摘 要高分子合成材料对人类的日常生活有着巨大的帮助，但大量高分子合成材料废弃物的焚烧也造成了严重的环境污染，开发可降解的高分子材料可以有效的解决这一问题。不饱和聚酯因其具有独特的可生物降解性而逐渐成为近年来的研发热点，但传统的不饱和聚酯产品的生产原料都来源于石油化工业，考虑到全球石油资源的现状，人类必须寻找一种代替石油原料的新的合成材料体系。本文以便宜易得且绿色环保的化工产品衣康酸为原料制备了一种新型不饱和聚酯。 此实验以衣康酸、己二酸和 1,4-丁二醇为原料采用了直接酯化-缩聚的方法合成了不饱和聚酯。通过醇酸比、摩尔比、催化剂种类、反应温度四个角度去寻找了不饱和聚酯的最佳合成条件，并通过红外光谱与核磁共振表征了聚酯的结构。通过实验数据可得最佳的合成条件温度为165℃、醇酸比为1.2：1、饱和酸与不饱和酸的摩尔比为8:2、催化剂为钛酸四丁酯。关键词：衣康酸 可生物降解性 环境污染Synthesisand characterization of unsaturated polyesterABSTRACTPolymer synthetic materials have great help to the daily life of human, but the incineration of a large amount of polymer materials waste also caused serious environmental pollution, and the development of degradable polymer materials can effectively solve this problem. Unsaturated polyester has become a hot research field in recent years due to its unique biodegradability, but the raw materials of traditional unsaturated polyester products come from petrochemical industry. considering the status of global petroleum resources, human must seek a new synthetic material system instead of petroleum raw materials. In this paper, a new type of unsaturated polyester was prepared from itaconic acid, which is easy to obtain and green environmental protection.In this experiment, the unsaturated polyester was synthesized by direct esterification and polycondensation using itaconic acid, adipic acid and 1,4-butanediol as raw materials. The optimum synthesis conditions of unsaturated polyester were found at four angles of molar ratio, molar ratio, catalyst type and reaction temperature, and the structure of polyester was characterized by IR and 1h NMR. Through the experimental data, the best synthesis conditions temperature is 165 ℃, the molar ratio of alcohol to acid is 1. 2: 1, the molar ratio of saturated acid to unsaturated acid is 8: 2, and the catalyst is tetrabutyl titanateKEY WORDS: itaconic acid,biodegradable，environmental pollution目 录前言11 文献综述21.1 不可生物降解的高分子材料的使用弊端1.2世界石油