酸性离子液体催化大豆油水解制备混合脂肪酸研究论文.docVIP

摘 要 本文研究了分别以1-磺酸丁基-3-甲基咪唑三氟甲磺酸盐和1-羧甲基-3-甲基咪唑四氟硼酸盐酸性离子液体作为催化剂，水解大豆油制备混合脂肪酸。利用单因素分析法讨论了水的用量、催化剂用量对油脂水解反应的影响，分析了水解率随温度和反应时间的变化趋势，利用正交实验考察最佳反应条件。实验结果表明：在较低温度下，1-磺酸丁基-3-甲基咪唑三氟甲磺酸盐酸性离子液体水解反应进行缓慢，在达到100 ℃为其的最佳使用温度，催化活性较高，水解反应明显加快。在固定温度100 ℃下，反应时间是最主要的影响因素，其次是催化剂用量、水用量。在单因素试验的基础上用正交试验得出优化工艺条件为：1-磺酸丁基-3-甲基咪唑三氟甲磺酸盐用量为油重的0.5%、水用量为油重的50%、反应时间为7 h、反应温度为100 ℃。在该条件下大豆油的水解产物酸值为42.14mgKOH/g，水解率为25.26%；在较低温度下，1-羧甲基-3-甲基咪唑四氟硼酸盐酸性离子液体水解反应进行缓慢，在达到100 ℃为其的最佳使用温度，催化活性较高，水解反应明显加快。在固定温度100 ℃下，反应时间是最主要的影响因素，其次是催化剂用量、水用量。在单因素试验的基础上用正交试验得出优化工艺条件为：1-羧甲基-3-甲基咪唑四氟硼酸盐用量为油重的0.5%、水用量为油重的50%、反应时间为7 h、反应温度为100 ℃。在该条件下大豆油的水解产物酸值为37.85mgKOH/g，水解率为22.69%。混合脂肪酸易分离、质量好、色泽浅、易于测定。 脂肪酸 Title Ionic Iiquids Catalyzed Hydrolysis of Soybean Oil Preparation of Fatty Acid Mixture Abstract In this paper, 1 - sulfobutyl -3-- methylimidazolium trifluoro methanesulfonate and1 - carboxymethyl -3-- methylimidazolium tetrafluoroborate as catalyst, preparation of mixed soybean oil fatty acid hydrolysis. Select several common emulsifiers on the hydrolysis of fat were compared using single factor analysis method of the amount of water, catalyst on fat hydrolysis reaction, analysis of the hydrolysis rate increases with temperature and reaction time trends, using the orthogonal experiment investigated the optimum reaction conditions. The results show that: at low temperatures, very low catalytic activity of 1 - sulfobutyl -3-- methylimidazolium trifluoro methanesulfonate, the hydrolysis reaction is slow, reaching 100 ℃ for the best use of ion exchange resin temperature, the higher catalytic activity, hydrolysis markedly accelerated. At a fixed temperature of 100 ℃, the amount of reaction time is the most important factors, followed by the catalyst amount, the amount of water. In the single-factor test based on orthogonal experiment showed that optimum conditions are: 1 - sulfobutyl -3-- methylimidazolium trifluoro methanesulfonate dosage of 0.5% oil weight,