材料保护投稿--武汉大学方鹏飞(3)-修改稿.doc

无机富锌底漆中锌粉对其性能的影响 陈吉罗敏陈宇豪林宏升何春清方鹏飞( (武汉大学物理科学与技术学院，湖北武汉，430072) [摘要] 为了研究无机富锌底漆中锌粉对其复合涂层体系防腐性能的影响，球状和片状制备了无机富锌底漆，环氧云铁中间漆、灰环氧面漆构成重防腐复合涂层体系，通过盐雾试验和电化学交流阻抗谱分体系的防腐性能。结果表明：片状无机富锌底漆的耐蚀性能更强，经过长时间的盐雾试验后表面没有出现明显的腐蚀产物；复合涂层体系交流阻抗谱的Bode图中低频阻抗模值在较长时间内稳定在107 Ω·cm2左右， Nyquist图中涂层体系的容抗弧半径明显增大，从涂层电容和电阻可以判定片状无机富锌涂层体系的防腐性能优于球状无机富锌涂层体系。 [关键词] 无机富锌；复合涂层；屏蔽作用；防腐性能 [中图分类号] TG174.45 [文献标识码] A erformance Chen Ji, Luo Min, Chen Yu-hao, Lin Hong-sheng, He Chun-qing, Fang Peng-fei (College of Physics and Technology Wuhan University, Hubei Wuhan 430072, China) Abstract: To study the effect of the shape of zinc in inorganic zinc primer to heavy anti-corrosion of its composite coatings, spherical and flake zinc was selected to prepare inorganic zinc primer, which was constituted heavy-duty composite coating with epoxy micaceous iron oxide intermediate paint, gray epoxy topcoat together, and the corrosion resistance of the primer and composite systems was investigsted by the salt spray test and electrochemical impedance spectroscopy. The results showed that: the corrosion resistance of the flake inorganic zinc-rich primer was stronger, obvious corrosion products did not appeared on its surface after a long period of salt spray test; to the flake inorganic zinc composite coating system, the low frequency impedance of the Bode diagram in composite coating systematic edance spectra stabled at around 107 Ω ? cm2 in a relatively long period, capacitive arc radius significantly increased in the Nyquist figure; the corrosion resistance of flake inorganic zinc coating system was better than the spherical inorganic rich zinc coating system from the values of capacitors and resistors of the composite coating system. Key words: inorganic zinc; composite coating; shielding effect; corrosion resistance 0前言 全世界每年因腐蚀造成的经济损失约为占各国国民生产总值GDP)的2％～4％[2][3]。 无机富锌是采用无机胶黏剂材料及锌粉组成的，其最大的特点是锌粉含量高达70%以上[1]。无机富锌的防护作用一般认为包括前期阴极保护作用和后期由于锌粉腐蚀产生的致密产物堵塞涂层孔隙而导致的屏蔽作用[2,3]。无机富锌中主要采用球状锌粉，腐蚀性介质不能通过片状锌渗透，必须绕过鳞片，沿着鳞片径渗入，客观上增加了渗透