高分子选论课件 活性聚合.pptVIP

?-N=N-C?3 ?* + *C?3 + N2 phenyl zao triphenyl methyl (PAT) ini ter Et2N-C-S-S-C-NEt2 2Et2N-C-S* S S S tetra ethyl thiuram disulfide(TD) ini, fer, ter ?-N=N-S? ?* + *S? + N2 phenyl zao triophenyl ini fer 1956, Takayuki Otsu, St/TD/h? 1981, Takayuki Otsu, mechanism different from that of initiated by AIBN results: 1) conversion?, MW? 2) continue to polymerize during adding monomer further ? h? 3) block copolymer ?3-C-C-?3 2*C?3 ~CH2-CHX-B ~CH2-CHX + B mechanism: AB A* + B* slow