焙烧镁铝水滑石对棉粕水提液中棉酚的吸附性能及吸附机理研究.DOCVIP

焙烧镁铝水滑石对棉酚的及机理研究 摘要：棉酚是天然存在的多酚醛化合物，抗癌抗病毒等生物活性，引起科学和医学领域的广泛关注。实验采用共沉淀法制备镁铝水滑石并通过焙烧得焙烧水滑石，以焙烧产物作为吸附剂吸附棉酚，研究了吸附洗脱性能，并对吸附机理进行探讨。实验结果表明，焙烧水滑石对棉酚的吸附符合Freundlich等温线，动力学过程遵守二级速率方程，XRD表明吸附为表面吸附，pH和FT-IRXPS结果表明静电相互作用和氢键为主要作用力。吸附剂重复使用性好 关键词：棉酚焙烧水滑石吸附机理 文献标识码：A 文章编号：1003-0174（ ） Study on ossypol in Extract of Cottonseed Meal by Mg-Al Calcined Layered Double Hydroxide Abstract Gossypol, a polyphenol aldehyde compound in nature, is of scientific and medical interest because of itsanti-cancer and anti-viral properties. In this research, Layered Double Hydroxide (LDH) was synthesized by co-precipitationmethod, then calcined Layered Double Hydroxide (cLDH) was obtained by calcinating . The adsorption and desorption properties were studied by using cLDH as adsorbent, and the adsorption mechanisms was discussed. Kinetic data were well ?tted by apseudo-second order kinetic model, and the equilibrium data were ?tted by the Freundlich model. XRD results?indicated that the adsorption was surface adsorption, and electrostatic interaction and hydrogen bonding were the main forces identi?ed by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and effect of initial pH. The elution rate of 90% ethanol was up to 60%, the purity of gossypol extracted from cottonseed was 86.06% by HPLC. Thermal regeneration for re-use of cLDH4 after gossypol sorption was feasible within the first three cycles. Key words gossypol, calcined Mg-Al layered double hydroxide, adsorption, mechanism 收稿日期：2017-04-11 作者简介：李克超，女，1991年出生，硕士，食品科学 通讯作者：王承明，男，1964年出生，教授、博士生导师，农产品加工与贮藏、食品安全、食品化学 前言 棉酚是存在于棉花色腺体中一种黄色多酚类化合物，具有抗生育、抗氧化、抗癌、抗病毒等生物活性，引起科学和医学领域的广泛关注。汉夔等采用H103大孔树脂吸附乙醇提取液中的棉酚，纯度可达83.6%，但吸附容量尚待提高。水滑石双金属氢氧化物(Layered Double Hydroxide，简写为LDH)八面体层状其比表面积大，对壬基酚因此本实验拟利用水滑石吸附分离棉酚水滑石，考察pH、温度等对棉酚吸附洗脱的影响，并通过热力学、动力学拟合方程，XRDXPS等探讨吸附机理，以期为棉酚 1材料与方法 1.1仪器与试剂 D8 ADVNCE X射线衍射分析仪英国马尔文仪器有限公司Nexus 470红外光谱分析仪美国梅特勤公司722可见光分光光度计上海菁华科技仪器有限公司ESCALAB 250Xi X射线光电子能谱仪美国赛默飞世尔科技有限公司 Mg(NO3)2?6H2O, Al(NO3)3?6H2O, Na2CO3