[英语学习]化学专业英语前言翻译.docVIP

3. Abstract Reactions between hexanuclear manganese pivalate with lanthanide salts (chlorides or nitrates), in the presence of potassium hydroxide, 2-pyridylmethanol and sodium azide leads to formation of a new family of hexaheteronuclear manganese–lanthanide clusters. 4. Abstract Two novel metal–organic frameworks of [M3(ptz)2(N3)4(H2O)2] (M = Zn(1), Cd(2)) (ptz = 5-(4-pyridyl)tetrazolate) have been prepared hydro(solvo)thermally by reactions of 4-cyanopyridine and excess NaN3 in the presence of zinc and cadmium chloride, respectively. The overall structure motif of complexes 1 and 2 show pillared layered frameworks and feature an unprecedented 3-nodal network with (3,5,6)-connectivity. The layer is of particular interest as it is constructed by μ1,1–N3? and μ1,1,3–N3? bridging modes, simultaneously. Furthermore, the solid fluorescent properties and TGA were studied. 5. Abstract Structural characterization of a new self assembled coordination polymer of CuII, hexamine (hmt) and benzoate (OBz), [Cu4(OBz)8(hmt)]n (1), reveals that it is a cubic non-interpenetrating diamondoid network formed by the coordination of the μ4-hmt ligand to a linear [Cu2(OBz)4] spacer. The magnetic study reveals that the Cu(II) ions are antiferromagnetically coupled (J = ? 323.5 cm?1) through the syn–syn carboxylate bridges. 6. Abstract Simple PET chemosensors based on anthracene show a selective turn-on fluorescence sensing for Cu2+. The flexible receptor is favorable for turn-on sensing due to chelation enhanced fluorescence. Interestingly, the turn-on fluorescence sensing for Cu2+ is hardly disturbed by the competitive cations and other highly prevalent species in biological and environmental systems, implying a potential in the biological and environmental applications. 7. Abstract Metallacyclodimeric complex of [(Me4en)Pd(L)]2(PF6)4 (Me4en = N,N,N′,N′-tetramethylethylenediamine; L = 1,3-bis(4-pyridyl)tetramethyldisiloxane) is a sensitive container for dioxane via appropriate size effec