[文学研究]chap6-2011W-a.pdfVIP

Chap. 6 Electronic Structure of Atoms 6.4 The Wave Behavior of Matter Heisenberg’s Uncertainty Principle 6.5 Quantum Mechanical Atomic Orbitals 6.6 Representation of Orbitals Chapter 6 The Wave Nature of Light Electromagnetic Radiation electric field component electric field component Electromagnetic Electromagnetic radiation has two radiation has two components: components: electric field and electric field and magnetic field magnetic field Magnetic field component Magnetic field component The two component are in perpendicular directions The two component are in perpendicular directions The electromagnetic spectrum Particle Nature of electromagnetic Particle Nature of electromagnetic radiation radiation I. Max Planck ’s “Quantum” I. Max Planck ’s “Quantum” Max Planck (1900): “Energy can be either emitted or absorbed by atoms only in discrete chunks ” of some minimum size.” .” Fixed amount • The energy of single quantum equals a constant times the frequency of radiation. E = h ⋅ν • Matter is allowed to emit or absorb energy in whole-number is allowed to emit or absorb energy in whole-number multiples of hν multiples of -34 Planck s constant h = 6.63×10 J / s • The 1918 Nobel Prize in physics-- The Quantum Theory. • The 1918 Nobel Prize in physics-- The Quantum Theory. Particle Nature o