合成氨气体脱硫技术进展中英.docVIP

合成氨气体脱硫技术的进展 Advances in Desulfurization Technology for Ammonia Production 摘要 全面回顾了国内、外湿式氧化法和干法脱硫技术的发展及技术进展,分析了各种技术的优势及存在的问题。 关键词 气体净化 脱硫 进展 Abstract An overall review is given of the development of the technology for we-t process oxidation and dry-process desulfurization and technological advances both at home and abroad, and an ana-lysis is made of the advantages of various technologies and their problems. Keywords gas purification desulfurization progress 在合成氨生产过程中,无论采用何种原料路线(煤、油、天然气)、何种工艺技术, In the process of ammonia production,no matter adopt what kind of raw material route (coal, oil, natural gas), what kind of technology 其粗合成气中都含有大量的CO2,以煤为原料的合成气中还含有多种硫化物。 Its crude syngas, contain large amounts of CO2 from coal as the raw material also contains a variety of sulfide in the syngas CO2和硫化物对氨合成催化剂有很强的毒性,因此在合成气进入氨合成塔之前,需将CO2和硫化物脱除,称为脱硫、脱碳工艺。 CO2 and sulfides of ammonia synthesis catalyst has very strong toxicity, so before the syngas into ammonia synthesis tower, CO2 and sulfide removal, must be referred to as desulfurization and decarburization process 几十年来,脱硫、脱碳工艺不断发展、进步,新工艺的开发和老工艺的改进大量涌现,本文不可能一一论述,只将典型的、常用的工艺及其进展加以汇总,供选择工艺时参考。 For decades, the Desulfurization and decarbonization technology continuous development and progress, the development of new process and old process improvement, this paper could not have one, will only typical, common process and progress of the summary, reference for choosing process. 　　1 脱硫技术的发展现状 Desulfurization technology development present situation 原料气脱除硫化物技术分为干法和湿法两大类,湿法脱硫又分为湿式氧化法和胺法。 Feed gas removing sulfide technology falls into two types: dry and wet, wet desulfurization is divided into wet oxidation method and the amine method 湿式氧化法是溶液吸收H2S后直接转化为单质硫,单质硫分离后溶液循环使用;胺法是将吸收的H2S在再生系统释放,然后将H2S送至克劳斯装置再转化为单质硫,溶液则循环使用。 Wet oxidation method is directly converted to elemental sulfur after solution absorbs H2S, elemental sulfur separation solution circulation after use; Amine method is to release absorption of H