MoleculeswithTwoHeavyAtoms教学幻灯片讲义.pptVIP

D. Pyramidalization of A2H4 As the atomic number of A increases in 12e A2H4 systems, the stability of the anti structure increases relative to that of the planar structure. Thus C2H4 and Si2H4 are predicted to be planar while Ge2H4 and Sn2H4 have the anti structure. Experimentally, Sn2R4 [R=-CH(SiMe3)2] is found to have the anti structure shown in 10.33. 10.33 The MOs of A2H4 that results from the in-phase and out-of-phase combinations of ss* on each AH2 (i.e., ss+* and ss-*) are shown in 10.34 together with the p and p* levels. 10.34 Let us consider how p and p* of planar A2H4 mix with th