共模板法一步合成绣球状BiOClBr固溶体光催化剂.DOCVIP

共模板法一步合成绣球状BiOCl/Br 溶体光催化剂 东北石油大学化学化工学院 以乙二醇/十二烷棊三甲基溴化铵（EG/DTAB）为共模板剂，一步制得BiOCl/Br 的固溶体光催化剂，利用X射线衍射仪、扫描电子显微镜、能谱仪、N2吸附-脱 附仪和紫外-可见漫反射光谱仪进行了表征.结果表明，与采用溶剂热法制得的 BiOCl分级微球相比，采用EG/DTAB共模板法制得的BiOCl/Br固溶体只有更明 显的分层结构，呈绣球状.同时，DTAB的Br-插入到BiOCl的晶格中，形成固溶 体，减小丫禁带宽度.绣球状BiOCl/Br固溶体具有比商用P25、二维BiOCl纳米 片和三维BiOCl分级微球更优异的可见光间接敏化降解染料性能，当 nDTAB/nKCl=O. 75时,制得的BiOCl/Br固溶体8 min内在可见光下对罗丹明B （Rh B）的降解率达到97.2%; 1 h后在可见光下对甲基橙（M0）的降解率达到 83. 6%. 关键词： 共模板法;乙二醇/十二烷基三中基溴化铵;绣球状BiOCl/Bi、W溶体光催化剂; 陈颖，女，，教授，主耍从事能源纳米材料研 究. 基金：国家自然科学基金（批准号资助 One-step Synthesis of Hydrangea-like BiOCl/Br Solid Solution Photocatalyst with Co-template Method CHEN Ying ZHAO Yu LI Ting HAN Xingyue School of Chemistry and ChemicalEng i ne ering, Northeast Petroleum University; Abstract： Hydrangea-like BiOCl/Br solid solution photocatalysts were prepared by using glycol/dodecyl trimethyl amonium bromide (EG/DTAB) co-template in one step. The catarysts were characterized by X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, N2 adsorption-desorption， and UVVis diffuse reflectance spectroscopy. The results showed that the BiOCl/Br solid solution obtained by the EG/DTAB co-template method had a layered structure like hydrangea, different from BiOCl hierarchical microspheres prepared by solvothermal method; the Br-of DTAB was inserted into the lattice of BiOCl to form a solid solution, reducing the band gap of BiOCL Ilydrangca-likc BiOCl/Br solid solution showed excellent photocatalytic activity for degradation of rhodamine B (Rh B) and methyl orange (MO) under visible light irradiation. When the molar ratio of DTAB to KC1 was 0. 75，the photocatalytic degradation rate of Rh B was 97. 2%within 8 min, and that of MO was 83. 6% with 1 h. Keyword： Co-template method; Glycol/dodecyl triniethyl amonium bromide (EG/DTAB); Hydrangea-like BiOCl/Br solid solution photocatalyst; 近几年，光催化技术在还原C02［l，2］、光解水制氢［3, 4］和降解冇机物［5, 6］等领 域取得Y优异的效果.14 02具有氧化性高、稳定性好、无毒无害、成本低和污染 小等优点，是目前应用最广泛的纳米光催化材料，但其禁带宽度为3. 2 e V,对 可见光利用