MTA方法固井二界面整体固化胶结试验.PDFVIP

　　　　　　 226 2010 4 　　　　　　　　PET ROLEUM EXPLORATION AND DEVELOPMENT 　　　　　　　Vol.37　No.2　 :1000-0747(2010)02-0226-06 MTA 顾军, 秦文政 (中国地质大学(武汉)资源学院) :国家自然科学基金项目40972103);国家高技术研究发展计划(863)项目(2007AA06Z205) :基于泥饼仿地成凝饼的科学构想, 采用力学性 评价(如胶结强度)、微观结构分析(如X 射线粉末衍射分析、热失 重分析、环境扫描电子显微镜分析)和流体溶蚀实验等方法对MTA 方法固井二界面整体固化胶结进行了实验研究。研究 结果表明:随着养护时间的延长, 用M TA 方法得到的固井二界面胶结强度较目前提高了37.81%～ 1 606.31%;泥饼与水 泥浆发生了局部的同步水化硬化反应, 且生成了少量的团状水化硅酸钙(CSH(Ⅰ))凝胶和片沸石类凝胶, 显示固井二界 面整体固化胶结;流体溶蚀实验表明, 采用目前方法, 养护成型的样品浸泡28 d 后, 泥饼还原成了浑浊的稀钻井液, 而用 MTA 方法得到的凝饼与水泥硬化体已胶结为 一体, 且凝饼未被溶蚀, 表现为杯内流体仍清澈。这印证了两 个事实:一是 泥饼仿地成了凝饼, 二是固井二界面已整体固化胶结。 图6 表1 参16 :固井二界面;泥饼仿地成凝饼(MTA);MTA 方 ;整体固化胶结;实验证据 :TE324　　　:A Experiments on integrated solidification and cementation of the cement-formation interface based on Mud Cake to Agglomerated Cake (MTA )method Gu Jun, Qin Wenzheng F acu lty of E ar th R esources, Ch ina Un iversity of Geosciences, Wuhan 430074, Ch ina ( ) Abstract:ased on the scientific conception of M ud Cake to Agglomerated Cake (M TA), the integrated solidification and cementation of cement-formation interface w as studied by mechanical evaluation, microstructure analysis (XRD, TG and ESEM), and fluid dissolution test.The results of mechanical evaluation show that, compared w ith the existing method, the bond strength of cement-formation interface increased by 37.81 %-1 606.31 % with M TA method.The results of microstructure analysis show that the synchronous hydration and hardening reaction betw een the mud cake and cement slurry occurred locally, and a little CSH(Ⅰ)gel and heulandite gel formed.The results of fluid dissolution test show that,